Coextruded, crosslinked multilayer polyolefin foam structures from recycled polyolefin foam material and methods of making the same

ABSTRACT

A physically crosslinked, closed cell continuous multilayer foam structure comprising at least one polypropylene/polyethylene coextruded foam layer is obtained. The multilayer foam structure is obtained by coextruding a multilayer structure comprising at least one foam composition layer, irradiating the coextruded structure with ionizing radiation, and continuously foaming the irradiated structure.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a divisional application of U.S. patent applicationSer. No. 14/586,745, filed Dec. 30, 2014, the entire contents of whichis incorporated herein by reference.

FIELD OF THE INVENTION

This invention relates to multilayer polyolefin foam structures. Moreparticularly, to coextruded, crosslinked polyolefin multilayer foamstructures.

BACKGROUND OF THE INVENTION

Over the past three decades, manufacturing businesses have beensuccessful in recycling many types of wastes: newspapers, cardboard,aluminum, steel, glass, various plastics, films, foams, etc. In the caseof plastics, there are certain types of plastic waste that do notreadily recycle into commercially viable new products. One such type ofwaste is metallized polyolefin material.

Metallized polyolefins are common in the food packaging industry asbarrier films. For example, metalized polyolefin films are used aspotato chip bags, snack bar wrappers, etc. Other applications ofmetalized polyolefin films, particularly polypropylene films, includethe packaging of electronic and medical devices as well as dielectricsin electronic film capacitors.

Another application of metallized polyolefins, particularlypolypropylene, is in the plating industry. Decorative chrome plating(trivalent chromium) of injection molded polypropylene is commonly foundon household and domestic appliances as well as on components of otherdurable and non-durable goods. In addition, also common is decorativevacuum metalizing of polypropylene and polyethylene molded parts andthermoformed sheets including, for example, confectionary trays.

Metal plating of polypropylene moldings is also not limited todecorative applications. Engineering requirements such as EMI and RFIshielding, electro-static dissipation, wear resistance, heat resistance,and thermal and chemical barriers at times necessitates the metalplating of polypropylene moldings.

Currently, there are various methods and systems for reclaiming andrecycling various films and foams, including films and foams containingmetallized polyolefins. In addition, as manufacturers are continuouslytrying to employ “greener” techniques in the manufacturing process,commercial uses for these recycled materials are increasing in demand.However, various problems arise whenever recycled material is used inthe manufacturing process.

SUMMARY OF THE INVENTION

Applicants have discovered that using recycled material to create foamstructures can cause unwanted surface variations on the foam. Theseunwanted surface variations can include unwanted surface roughness,unwanted surface softness, unwanted surface firmness, unwanted surfaceenergy, and unwanted surface adhesive compatibility among others. Incertain commercial applications, such as in the automotive interior trimindustry, the surface properties of the foam are critical. When used forautomotive interior trim, laminators will normally laminate a film,fabric, fiber layer, or leather to the foam. The foam laminate thentypically can be thermoformed onto a hard polypropylene, ABS, or woodfiber composite substrate. In order for the foam laminate formationand/or the foam laminate thermoformed formation to be successful, thefoam surfaces should be consistent. Surface variations on the foamsurfaces can negatively affect lamination strength and quality.

An example of undesirable surface characteristics is illustrated inFIGS. 5A and 5B. The foams in FIGS. 5A and 5B contain 8% parts perhundred parts resin (“PPHR”) shredded (but not cryogenically pulverized)factory scrap crosslinked polypropylene/polyethylene blended foam. Asshown in FIGS. 5A-5B, dark spots and “gels” can be seen as black coloredrecycled foam that has not been fully broken down, dispersed, andotherwise reincorporated into these foam sheets. These spots and “gels”can cause problems for a laminator attaching a film, fabric, fiberlayer, or leather to these foams. Specifically, adhesion at the “gel”may be poorer and may delaminate during a secondary operation such asthermoforming, causing a visible blister-like defect on the film,fabric, fiber layer, or leather.

Applicants have discovered coextruded multilayer foam structuresincluding a surface foam layer(s) derived from virgin (non-recycled)polyolefin material and an interior foam layer(s) derived from one ormore recycled polyolefin materials. In addition, these foam structurescan include the recycled foam layer(s) sandwiched or buried between twonon-recycled foam layers. Accordingly, these multilayer foam structurescan allow manufacturers to continue to use recycled material to createlower cost and more environmentally friendly products that can performto the same standards as a foam structures made entirely fromnon-recycled material.

Described are multilayer foam structures and methods of making and usingthese structures. More particularly, described are formulations of aphysically crosslinked, co-extruded continuous multilayer foamstructures with a closed cell morphology. These formulations can utilizerecycled polyolefin material and incorporate it into a layer. As recitedherein, a “structure” includes, but is not limited to, layers, films,webs, sheets, or other similar structures.

Some embodiments include methods of forming multilayer structures bycoextruding a foam layer and a film layer on a side of the foam layer.The foam layer can include polypropylene and/or polyethylene and achemical foaming agent. The foam layer can also include a crosslinkingagent and the chemical foaming agent can be azodicarbonamide. The filmlayer can include polypropylene and/or polyethylene. The polypropylenein either layer can have a melt flow index of 0.1-25 grams per 10minutes at 230° C. The polyethylene in either layer can have a melt flowindex of 0.1-25 grams per 10 minutes at 190° C.

In some embodiments, theses coextruded structures can be irradiated withionizing radiation. The coextruded structures may be irradiated up to 4separate times. The ionizing radiation may be alpha rays, beta rays,gamma rays, or electron beams. Furthermore, the ionizing radiation maybe an electron beam with an acceleration voltage of 200-1500 kV. Thedosage of the electron beam may be 10-500 kGy. The ionizing radiationcan crosslink the coextruded structures to a crosslinking degree of20-75%.

In some embodiments, the irradiated, coextruded structures may also befoamed. The foaming process can be continuous to form foam structures.The foaming may include heating the irradiated structures with moltensalt, radiant heaters, vertical hot air oven, horizontal hot air oven,microwave energy, or a combination thereof.

The multilayer foamed structures can have a density of 20-250 kg/m³ anda thickness of 0.2-50 mm. In addition, the foam layer can have anaverage closed cell size of 0.05-1.0 mm and a mean surface roughness ofless than 80 μm.

Some embodiments include methods of forming multilayer structures bycoextruding a first foam layer and a second foam layer on a side of thefirst foam layer. The first foam layer can include polypropylene and/orpolyethylene and a first chemical foaming agent. The second foam layercan include polypropylene and/or polyethylene and a second chemicalfoaming agent. The polypropylene in either layer can have a melt flowindex of 0.1-25 grams per 10 minutes at 230° C. The polyethylene ineither layer can have a melt flow index of 0.1-25 grams per 10 minutesat 190° C. The first and/or second foam layers can also include acrosslinking agent. Furthermore, the first and/or second chemicalfoaming agent can be azodicarbonamide.

In some embodiments, theses coextruded structures can be irradiated withionizing radiation. The coextruded structures may be irradiated up to 4separate times. The ionizing radiation may be alpha rays, beta rays,gamma rays, or electron beams. Furthermore, the ionizing radiation maybe an electron beam with an acceleration voltage of 200-1500 kV. Thedosage of the electron beam may be 10-500 kGy. The ionizing radiationcan crosslink the coextruded structures to a crosslinking degree of20-75%.

In some embodiments, the irradiated, coextruded structures may also befoamed. The foaming process can be continuous to form foam structures.The foaming may include heating the irradiated structures with moltensalt, radiant heaters, vertical hot air oven, horizontal hot air oven,microwave energy, or a combination thereof.

The multilayer foamed structures can have a density of 20-250 kg/m³ anda thickness of 0.2-50 mm. In addition, the multilayer foam structure canhave an average closed cell size of 0.05-1.0 mm. Furthermore, the firstfoam layer and/or the second foam layer can have a mean surfaceroughness of less than 80 μm.

Some embodiments include methods of forming multilayer structures bycoextruding a first layer and a second layer on a side of the firstlayer. The first layer can include polypropylene and/or polyethylene anda first chemical foaming agent. The second layer can include 5-75 wt. %recycled metallized polyolefin material; 25-95 wt. % polypropylene,polyethylene, or a combination of polypropylene and polyethylene; and asecond chemical foaming agent. Furthermore, a third layer can becoextruded on a side of the second layer opposite the first layer. Thethird layer can comprise polypropylene and/or polyethylene and a thirdchemical foaming agent. In addition, the first and/or third layer can besubstantially free of recycled polyolefin material. Furthermore, any orall of the first, second, or third layers can include a crosslinkingagent. In addition, any or all of the first, second, or third chemicalfoaming agents can be azodicarbonamide. The polypropylene in any layercan have a melt flow index of 0.1-25 grams per 10 minutes at 230° C. Thepolyethylene in any layer can have a melt flow index of 0.1-25 grams per10 minutes at 190° C.

The recycled metallized polyolefin material can be small enough to passthrough a standard sieve of 0.375 inches. Furthermore, the recycledmetallized polyolefin material may have had a metal layer(s) with anoverall thickness of 0.003-100 μm, prior to being recycled.

In some embodiments, theses coextruded structures can be irradiated withionizing radiation. The coextruded structures may be irradiated up to 4separate times. The ionizing radiation may be alpha rays, beta rays,gamma rays, or electron beams. Furthermore, the ionizing radiation maybe an electron beam with an acceleration voltage of 200-1500 kV. Thedosage of the electron beam may be 10-500 kGy. The ionizing radiationcan crosslink the coextruded structures to a crosslinking degree of20-75%.

In some embodiments, the irradiated, coextruded structures may also befoamed. The foaming process can be continuous to form foam structures.The foaming may include heating the irradiated structures with moltensalt, radiant heaters, vertical hot air oven, horizontal hot air oven,microwave energy, or a combination thereof.

The multilayer foamed structures can have a density of 20-250 kg/m³ andcan have a thickness of 0.2-50 mm. In addition, the multilayer foamstructure can have an average closed cell size of 0.05-1.0 mm.Furthermore, the first foam layer and/or the third foam layer can have amean surface roughness of less than 80 μm.

Some embodiments include a multilayer foam structure that has acoextruded first foam layer including polypropylene and/or polyethyleneand a coextruded second foam layer on a side of the first foam layer.The second foam layer can include 5-75 wt. % recycled metallizedpolyolefin material and 25-95 wt. % polypropylene, polyethylene, or acombination of polypropylene and polyethylene. The multilayer foamstructure can also include a coextruded third foam layer on a side ofthe second foam layer opposite the first foam layer. The third layer caninclude polypropylene and/or polyethylene. The first foam layer and/orthe third foam layer can be substantially free of recycled polyolefinmaterial. The polypropylene in any layer can have a melt flow index of0.1-25 grams per 10 minutes at 230° C. The polyethylene in any layer canhave a melt flow index of 0.1-25 grams per 10 minutes at 190° C.

The multilayer foamed structures can have a density of 20-250 kg/m³ andcan have a thickness of 0.2-50 mm. In addition, the multilayer foamstructure can have an average closed cell size of 0.05-1.0 mm. Themultilayer foam structure can also have a crosslinking degree of 20-75%.Furthermore, the first foam layer and/or the third foam layer can have amean surface roughness of less than 80 μm. In addition, in someembodiments the multilayer foam structure may be slit, friction sawed,sheared, heat cut, laser cut, plasma cut, water jet cut, die-cut,mechanically cut, or manually cut to form an article.

Some embodiments include a laminate that includes a multilayer foamstructure and a laminate layer. The multilayer foam structure caninclude a coextruded first foam layer that includes polypropylene and/orpolyethylene and a second coextruded foam layer on a side of the firstfoam layer. The second foam layer can include 5-75 wt. % recycledmetallized polyolefin material and 25-95 wt. % polypropylene,polyethylene, or a combination of polypropylene and polyethylene. Thelaminate layer can be on a side of the first foam layer opposite thesecond foam layer. The laminate layer can be a film, fabric, fiberlayer, or a leather. The first foam layer can have a mean surfaceroughness less than 80 μm. The multilayer foam structure can alsoinclude a coextruded third foam layer on a side of the second foam layeropposite the first foam layer. The third layer can include polypropyleneand/or polyethylene. The first and/or third layers can be substantiallyfree of recycled polyolefin material. In addition, the laminate canfurther be thermoformed onto a substrate such that the substrate is on aside of the third foam layer opposite the second foam layer.

Some embodiments include methods of forming multilayer structures bycoextruding a first layer and a second layer on a side of the firstlayer. The first layer can include polypropylene and/or polyethylene anda first chemical foaming agent. The second layer can include 5-50 wt. %recycled, crosslinked polyolefin foam material; 50-95 wt. %polypropylene, polyethylene, or a combination of polypropylene andpolyethylene; and a second chemical foaming agent. Furthermore, a thirdlayer can be coextruded on a side of the second layer opposite the firstlayer. The third layer can comprise polypropylene and/or polyethyleneand a third chemical foaming agent. In addition, the first and/or thirdlayer can be substantially free of recycled polyolefin material.Furthermore, any or all of the first, second, or third layers caninclude a crosslinking agent. In addition, any or all of the first,second, or third chemical foaming agents can be azodicarbonamide. Thepolypropylene in any layer can have a melt flow index of 0.1-25 gramsper 10 minutes at 230° C. The polyethylene in any layer can have a meltflow index of 0.1-25 grams per 10 minutes at 190° C.

The recycled, crosslinked polyolefin foam material can be cryogenicallypulverized polyolefin foam material. The cryogenically pulverizedpolyolefin foam material can be small enough to pass through a 3.5 U.S.Standard mesh.

In some embodiments, theses coextruded structures can be irradiated withionizing radiation. The coextruded structures may be irradiated up to 4separate times. The ionizing radiation may be alpha rays, beta rays,gamma rays, or electron beams. Furthermore, the ionizing radiation maybe an electron beam with an acceleration voltage of 200-1500 kV. Thedosage of the electron beam may be 10-500 kGy. The ionizing radiationcan crosslink the coextruded structures to a crosslinking degree of20-75%.

In some embodiments, the irradiated, coextruded structures may also befoamed. The foaming process can be continuous to form foam structures.The foaming may include heating the irradiated structures with moltensalt, radiant heaters, vertical hot air oven, horizontal hot air oven,microwave energy, or a combination thereof.

The multilayer foamed structures can have a density of 20-250 kg/m³ andcan have a thickness of 0.2-50 mm. In addition, the multilayer foamstructure can have an average closed cell size of 0.05-1.0 mm.Furthermore, the first foam layer and/or the third foam layer can have amean surface roughness of less than 80 μm.

Some embodiments include a multilayer foam structure that has acoextruded first foam layer including polypropylene and/or polyethyleneand a coextruded second foam layer on a side of the first foam layer.The second foam layer can include 5-50 wt. % recycled, crosslinkedpolyolefin foam material and 50-95 wt. % polypropylene, polyethylene, ora combination of polypropylene and polyethylene. The multilayer foamstructure can also include a coextruded third foam layer on a side ofthe second foam layer opposite the first foam layer. The third layer caninclude polypropylene and/or polyethylene. The first foam layer and/orthe third foam layer can be substantially free of recycled polyolefinmaterial. The polypropylene in any layer can have a melt flow index of0.1-25 grams per 10 minutes at 230° C. The polyethylene in any layer canhave a melt flow index of 0.1-25 grams per 10 minutes at 190° C. Therecycled, crosslinked polyolefin foam material can include cryogenicallypulverized polyolefin foam material.

The multilayer foamed structures can have a density of 20-250 kg/m³ andcan have a thickness of 0.2-50 mm. In addition, the multilayer foamstructure can have an average closed cell size of 0.05-1.0 mm. Themultilayer foam structure can also have a crosslinking degree of 20-75%.Furthermore, the first foam layer and/or the third foam layer can have amean surface roughness of less than 80 μm. In addition, in someembodiments the multilayer foam structure may be slit, friction sawed,sheared, heat cut, laser cut, plasma cut, water jet cut, die-cut,mechanically cut, or manually cut to form an article.

Some embodiments include a laminate that includes a multilayer foamstructure and a laminate layer. The multilayer foam structure caninclude a coextruded first foam layer that includes polypropylene and/orpolyethylene and a second coextruded foam layer on a side of the firstfoam layer. The second foam layer can include 5-50 wt. % recycled,crosslinked polyolefin foam material and 50-95 wt. % polypropylene,polyethylene, or a combination of polypropylene and polyethylene. Thelaminate layer can be on a side of the first foam layer opposite thesecond foam layer. The laminate layer can be a film, fabric, fiberlayer, or a leather. The first foam layer can have a mean surfaceroughness less than 80 μm. The recycled, crosslinked polyolefin foammaterial can include cryogenically pulverized polyolefin foam material.The multilayer foam structure can also include a coextruded third foamlayer on a side of the second foam layer opposite the first foam layer.The third layer can include polypropylene and/or polyethylene. The firstand/or third layers can be substantially free of recycled polyolefinmaterial. In addition, the laminate can further be thermoformed onto asubstrate such that the substrate is on a side of the third foam layeropposite the second foam layer.

It is understood that aspects and embodiments of the invention describedherein include “consisting” and/or “consisting essentially of” aspectsand embodiments. For all methods, systems, compositions, and devicesdescribed herein, the methods, systems, compositions, and devices caneither comprise the listed components or steps, or can “consist of” or“consist essentially of” the listed components or steps. When a system,composition, or device is described as “consisting essentially of” thelisted components, the system, composition, or device contains thecomponents listed, and may contain other components which do notsubstantially affect the performance of the system, composition, ordevice, but either do not contain any other components whichsubstantially affect the performance of the system, composition, ordevice other than those components expressly listed; or do not contain asufficient concentration or amount of the extra components tosubstantially affect the performance of the system, composition, ordevice. When a method is described as “consisting essentially of” thelisted steps, the method contains the steps listed, and may containother steps that do not substantially affect the outcome of the method,but the method does not contain any other steps which substantiallyaffect the outcome of the method other than those steps expresslylisted.

In the disclosure, “substantially free of” a specific component, aspecific composition, a specific compound, or a specific ingredient invarious embodiments, is meant that less than about 5%, less than about2%, less than about 1%, less than about 0.5%, less than about 0.1%, lessthan about 0.05%, less than about 0.025%, or less than about 0.01% ofthe specific component, the specific composition, the specific compound,or the specific ingredient is present by weight. Preferably,“substantially free of” a specific component, a specific composition, aspecific compound, or a specific ingredient indicates that less thanabout 1% of the specific component, the specific composition, thespecific compound, or the specific ingredient is present by weight.

Additional advantages of this invention will become readily apparent tothose skilled in the art from the following detailed description. Aswill be realized, this invention is capable of other and differentembodiments, and its details are capable of modifications in variousobvious respects, all without departing from this invention.Accordingly, the examples and description are to be regarded asillustrative in nature and not as restrictive.

BRIEF DESCRIPTION OF THE DRAWINGS

Exemplary embodiments of the invention will now be described withreference to the accompanying figures, in which:

FIG. 1A is a backlit magnified photograph of the foam of Example 1;

FIG. 1B is a frontlit non-magnified photo of the foam of Example 1;

FIG. 1C is a backlit magnified photograph of the unfoamed Example 1;

FIG. 2A is a backlit magnified photograph of the foam of Example 2;

FIG. 2B is a frontlit non-magnified photo of the foam of Example 2;

FIG. 2C is a backlit magnified photograph of the unfoamed Example 2;

FIG. 3A is a first backlit magnified photograph of the foam of Example3;

FIG. 3B is a second backlit magnified photograph of the foam of Example3;

FIG. 3C is a first frontlit non-magnified photo of the foam of Example3;

FIG. 3D is a second frontlit non-magnified photo of the foam of Example3;

FIG. 3E is a backlit magnified photograph of the unfoamed Example 3;

FIG. 4A is a backlit magnified photograph of the foam of Example 4;

FIG. 4B is a frontlit non-magnified photo of the foam of Example 4;

FIG. 4C is a backlit magnified photograph of the unfoamed Example 4;

FIG. 5A is a first photo of a foam containing shredded recycled,crosslinked polyolefin foam.

FIG. 5B is a second photo of a foam containing shredded recycled,crosslinked polyolefin foam.

DETAILED DESCRIPTION OF THE INVENTION

Described are methods of producing crosslinked, closed cell coextrudedmultilayer foam structures. A layer or layers of the multilayer foamstructure can be derived from recycled polyolefin material. The methodsfor producing a crosslinked, closed cell co-extruded multilayer foamstructure including a recycled polyolefin foam layer may include thesteps of (a) co-extrusion, (b) irradiation, and (c) foaming.

Co-extrusion is the extrusion of multiple layers of materialsimultaneously. This type of extrusion utilizes two or more extruders todeliver a steady volumetric throughput of material to an extrusion head(die) which can extrude the materials in the desired form.

In the co-extrusion step, foam compositions can be fed into multipleextruders to form an unfoamed, multilayer structure. For example, an “A”foam composition can be fed into one extruder and a “B” foam compositioncan be fed into a second extruder. The method of feeding ingredientsinto the extruders can be based on the design of the extruder and thematerial handling equipment available. Preblending ingredients of thefoam compositions may be performed, if necessary, to facilitate theirdispersal. A Henshel mixer can be used for such preblending. Allingredients can be preblended and fed thru a single port in theextruder. The ingredients can also be individually fed thru separatedesignated ports for each ingredient. For example, if the crosslinkingpromoter or any other additive is a liquid, the promoter and/oradditives can be added through a feeding gate (or gates) on the extruderor through a vent opening on the extruder (if equipped with a vent)instead of being preblended with solid ingredients. Combinations of“preblending” and individual ingredient port feeding can also beemployed.

Each extruder can deliver a steady amount of each composition into oneor more manifolds followed by a sheeting die to create an unfoamedco-extruded multilayer sheet. There are two common methods forco-extruding materials: (1) feed block manifolds; and (2)multi-manifolds within the die. Elements of a feed block manifold caninclude: (a) inlet ports for the upper, middle, and lower layers; (b) astreamlined melt lamination area that channels separate flow streamsinto one laminated melt stream inside the feed block; (c) an adapterplate between the feed block and the sheet die; and/or (d) a sheet die(similar to monolayer die), wherein the laminated melt stream enters thecenter of the die and spreads out along the manifold flowing out of thedie exit as a distinct multilayer extrudate. Elements of amulti-manifold die can be: (a) similar to a monolayer die, except thatthere is more than one feed channel; (b) that each melt channel has itsown choker bar for flow control; and/or (c) that the melt streamsconverge inside the die near the exit and emerge as a distinctmultilayer extrudate.

Layer thicknesses can be determined by the design of the manifold(s) anddie. For example, an 80/20 feed block manifold can deliver compositionsin approximately a 4:1 ratio when the speed and size of each extruder ismatched accordingly. This ratio can be altered by changing, for example:(a) the relative extrusion speed between one extruder and another; (b)the relative size of each extruder; and/or (c) the composition (i.e.,the viscosity) of the individual layers.

The thickness of the overall multilayer sheet can be controlled by theoverall die gap. However, the overall multilayer sheet thickness canfurther be adjusted, for example, by stretching (i.e., “drawing”) themelted multilayer extrudate and/or flattening the melted multilayerextrudate through a nip.

The multilayer structures can include at least 2 layers made up ofdifferent compositions. In some embodiments, the multilayer structuresinclude at least 2 layers made up of different foam compositions. Insome embodiments, the multilayer structure includes at least onenon-recycled polyolefin layer and at least one recycled polyolefinlayer. For example, the structure can be an A/B layered structure, A/B/Alayered structure, A/B/C layered structure, or can have multiple otherlayers. In some structures, the B layer can include recycled polyolefinmaterial and the A layer can include non-recycled polyolefin material.However, both the A, B, and other layers can be made up of non-recycledpolyolefin material or recycled polyolefin material as well.Furthermore, the multilayer structures can include additional layerssuch as tie layers, film layers, and/or additional foam layers(including additional recycled and/or non-recycled layers) among others.

The foam composition fed into the extruder to form the non-recycledlayer(s) can include at least one polypropylene, at least onepolyethylene, or a combination thereof. These polypropylene(s) and/orpolyethylene(s) include the same types described below with regard tothe recycled metallized polyolefin material. That is, the polypropyleneincludes, but is not limited to, polypropylene, impact modifiedpolypropylene, polypropylene-ethylene copolymer, impact modifiedpolypropylene-ethylene copolymer, metallocene polypropylene, metallocenepolypropylene-ethylene copolymer, metallocene polypropylene olefin blockcopolymer (with a controlled block sequence), polypropylene basedpolyolefin plastomer, polypropylene based polyolefin elasto-plastomer,polypropylene based polyolefin elastomer, polypropylene basedthermoplastic polyolefin blend and polypropylene based thermoplasticelastomeric blend. Furthermore, the polypropylenes may be grafted withmaleic anhydride. In addition, the polyethylene includes, but is notlimited to, LDPE, LLDPE, VLDPE, VLLDPE, HDPE, polyethylene-propylenecopolymer, metallocene polyethylene, metallocene ethylene-propylenecopolymer, and metallocene polyethylene olefin block copolymer (with acontrolled block sequence), any of which may contain graftedcompatibilizers or copolymers that contain acetate and/or ester groups.These polyethylenes may be grafted with maleic anhydride. Thesepolyethylenes may also be copolymers and terpolymers containing acetateand/or ester groups and may be copolymer and terpolymer ionomerscontaining acetate and/or ester groups. The foam composition fed intothe extruder to form the non-recycled layer(s) can include at leastabout 75 wt. % non-recycled polypropylene, polyethylene, or acombination thereof, preferably at least about 90 wt. %, more preferablyat least about 95 wt. %, and even more preferably at least about 98 wt.%. In addition, the foam compositions fed into the extruder to form thenon-recycled layer(s) can be substantially free of recycled polyolefinmaterial. The foam compositions fed into the extruder to form thenon-recycled layer(s) can also be 100 wt. % virgin or non-recycledmaterial.

Since a broad range of multilayer foam articles and laminates can becreated with the disclosed foam compositions, a broad range ofpolypropylenes and polyethylenes can be employed in the foamcompositions to meet the various end use requirements of the structures,articles, and laminates.

The foam compositions fed into the extruders to form the recycledlayer(s) can include recycled material including, but not limited to,recycled polyolefin material, recycled metallized polyolefin material,recycled polyolefin film material, recycled polyolefin metallized filmmaterial, recycled polyolefin foam material, recycled polyolefinmetallized foam material, or combinations thereof. The foam compositionfed into the extruder to form the recycled layer(s) can include at leastabout 5 wt. % recycled material, preferably at least about 10 wt. %, andmore preferably at least about 15 wt. %. In addition, these foamcompositions fed into the extruders to form the recycled layer(s) caninclude at least about 25 wt. %, preferably at least about 30 wt. %, andmore preferably at least about 40 wt. % polypropylene, polyethylene, orcombinations thereof.

When the foam compositions fed into the extruder to form the recycledlayer(s) includes recycled metallized polyolefin material, the foamcomposition can include about 5 to about 75 wt. % recycled metallizedpolyolefin material, preferably from about 10 to about 70 wt. %, andmore preferably from about 20 to about 60 wt. %. In addition, theserecycled metallized polyolefin foam compositions can include about 25 toabout 95 wt. %, preferably about 30 to about 90 wt. %, and morepreferably about 40 to about 80 wt. % polypropylene, polyethylene, orcombinations thereof.

Recycled metallized polyolefin material is available in various forms.Examples include, but are not limited to: pellets, granules, chips,flakes, beads, cylinders, rods, fluff, and powder. In some embodiments,recycled metallized polyolefin material can be obtained as homogenouspellets utilizing the process disclosed in WO 2013057737 A2, which ishereby incorporated by reference in its entirety. In some embodiments,chips or flakes of recycled metallized polyolefin material can beobtained from plastic chippers and shredders commonly used to reduce thesize of waste profiles, injection molded pieces, etc. In a thirdexample, pulverized metallized polyolefin material can be obtained fromcommercial pulverizing equipment or cryogenic pulverization.

Regardless of the form, it can be preferred that the recycled materialpieces be reduced in size to pass thru a standard sieve of about 0.375inches (9.5 mm). Recycled pieces that do not pass thru a standard sieveof about 0.375 inches (9.5 mm) can be difficult to sufficiently shearand mix with other ingredients within the extruder. Thus, a homogenousstructure may not be obtained.

The primary sources of metallized polyolefins are the metalizing andmetal coating industries. These industries employ various techniques toobtain metallized polyolefins, including vacuum metallization, arc orflame spraying, electroless plating, or electroless plating followed byelectroplating. The coatings are often not limited to one metalliclayer. Polyolefin coated with multiple layers of varying metalsdeposited using different techniques can also be used in the disclosedinvention.

Metallized polyolefins can be obtained by vacuum metallization, arc orflame spraying, electroless plating, or electroless plating followed byelectroplating. Each technique to obtain metallized polyolefins isbriefly described as follows:

In vacuum metallization, a metal is evaporated in a vacuum chamber. Thevapor then condenses onto the surface of the substrate, leaving a thinlayer of metal coating. This deposition process is also commonly calledphysical vapor deposition (PVD).

In flame spraying, a hand-held device is used to spray a layer ofmetallic coating on the substrate. The primary force behind depositionis a combustion flame, driven by oxygen and gas. Metallic powder isheated and melted. The combustion flame accelerates the mixture andreleases it as a spray.

Arc spraying is similar to flame spraying, but the power source isdifferent. Instead of depending on a combustion flame, arc sprayingderives its energy from an electric arc. Two wires, composed of themetallic coating material and carrying DC electric current, touchtogether at their tips. The energy that releases, when the two wirestouch, heats and melts the wire, while a stream of gas deposits themolten metal onto the surface of the substrate, creating a metal layer.

In electroless plating, the surface of the plastic is etched away usingan oxidizing solution. The surface becomes extremely susceptible tohydrogen bonding as a result of the oxidizing solution and typicallyincreases during the coating application. Coating occurs when thepolyolefin component (post-etching) is immersed in a solution containingmetal ions, which then bond to the plastic surface as a metal layer.

In order for electroplating (electrolytic plating) to be successful, thepolyolefin surface must first be rendered conductive, which can beachieved through electroless plating. Once the polyolefin surface isconductive, the substrate is immersed in a solution. In the solution aremetallic salts, connected to a positive source of current (cathode). Ananodic (negatively charged) conductor is also placed in the bath, whichcreates an electrical circuit in conjunction with the positively chargedsalts. The metallic salts are electrically attracted to the substrate,where they create a metal layer. As this process happens, the anodicconductor, typically made of the same type of metal as the metallicsalts, dissolves into the solution and replaces the source of metallicsalts, which is depleted during deposition.

The amount of coating that can be deposited by each technique varies.Depending on the end use requirements, one technique may be preferableover another. Nonetheless, the metal coatings deposited by thesetechniques will range from about 0.003 μm for a single layer to 100 μmfor a multi-layer coating, preferably from 0.006 μm for a single layerto 75 μm for a multi-layer coating, and more preferably from 0.01 to μmfor a single layer to 50 μm for a multi-layer coating. The metal in therecycled metallized polyolefins varies from about 0.05 to about 5 wt. %.

The most common metal coating applied to polyolefins is aluminum. Lesscommon coatings are trivalent chromium, nickel, and copper. Even lesscommon coatings are, but not limited to, tin, hexavalent chromium, gold,silver, as well as co-deposited metals such as nickel-chromium. Thoseskilled in the art will appreciate that these metal coatings are notnecessarily pure elemental coatings. For example, “nickel” may benickel-phosphorus or nickel-boron alloy and “copper” may be copper-zincalloy (brass) or copper-tin alloy (bronze). Regardless of whether themetal is or isn't alloyed, the specific metal is still the primarycomponent of the coating. It can be preferred that the metallic coatingcontain 70-100% of the named metal, more preferably 80-100% of the namedmetal, and even more preferably 85-100% of the named metal. Thoseskilled in the art will also appreciate that the surface of the metallayers can be oxidized, and some of the metals, tarnished.

Both polypropylene and polyethylene films can be vacuum metalized in thefilm metallizing industry. It should thus be expected that any recycledmetallized polyolefin can contain at least one polypropylene, or atleast one polyethylene, or a mixture of both. For barrier applications(rather than decorative applications), both polypropylene andpolyethylene films may be coextruded with other barrier layer materials,such as EVOH and PVOH. In such instances, these multilayer films canhave adhesive “tie layers” to bond the EVOH and PVOH to thepolypropylene or polyethylene. These tie layers range in polyolefinsfrom OBC to polyethylene with acetate or ester groups to polyethyleneionomers.

Likewise, polypropylenes and polyethylenes grafted with maleic anhydrideare also used in the industry to improve adhesion, not only withadjoining EVOH or PVOH but also with the metal coatings.

In the metal coatings industry, polypropylene may often be preferredover polyethylene. However, due to the broader end use requirements forarticles produced in this industry, polypropylenes may be blended withother olefins to meet, for example, softness requirements, impactrequirements, or adhesion requirements, etc. Thus, it should be expectedthat any recycled metallized polyolefin from this industry may be ablended polyolefin.

The polypropylene(s) comprising the polyolefin component of the recycledpolyolefin may contain an elastic or softening component, typically anethylene, α-olefin, or rubber component. Thus, the term “polypropylene”in this disclosure includes, but is not limited to, polypropylene,impact modified polypropylene, polypropylene-ethylene copolymer, impactmodified polypropylene-ethylene copolymer, metallocene polypropylene,metallocene polypropylene-ethylene copolymer, metallocene polypropyleneolefin block copolymer (with a controlled block sequence), polypropylenebased polyolefin plastomer, polypropylene based polyolefinelasto-plastomer, polypropylene based polyolefin elastomer,polypropylene based thermoplastic polyolefin blend and polypropylenebased thermoplastic elastomeric blend.

A non-limiting example of “polypropylene” is an isotactichomopolypropylene. Commercially available examples include, but are notlimited to, FF018F from Braskem, 3271 from Total Petrochemicals, andCOPYLENE™ CH020 from Conoco.

A non-limiting example of an “impact modified polypropylene” is ahomopolypropylene with ethylene-propylene (EP) copolymer rubber. Therubber can be amorphous or semicrystalline but is not in sufficientquantities to render the material any plastomeric or elastomericproperties. A few non-limiting examples of commercially available“impact modified polypropylene” are TI4015F and TI4015F2 from Braskemand Pro-fax® 8623 and Pro-fax® SB786 from LyondellBasell.

“Polypropylene-ethylene copolymer” is polypropylene with random ethyleneunits. A few non-limiting examples of commercially available“polypropylene-ethylene copolymer” are 6232, 7250FL, and Z9421 fromTotal Petrochemicals and TR3020F from Braskem.

“Impact modified polypropylene-ethylene copolymer” is polypropylene withrandom ethylene units and with ethylene-propylene (EP) copolymer rubber.The rubber can be amorphous or semicrystalline, but is not in sufficientquantities to render the material any plastomeric or elastoplastomericproperties. A non-limiting example of a commercially available impactmodified polypropylene-ethylene copolymer is PRISMA™ 6910 from Braskem.

“Metallocene polypropylene” is metallocene syndiotactichomopolypropylene, metallocene atactic homopolypropylene, andmetallocene isotactic homopolypropylene. Non-limiting examples of“metallocene polypropylene” are those commercially available under thetrade names METOCENE™ from LyondellBasell and ACHIEVE™ from ExxonMobil.Metallocene polypropylenes are also commercially available from TotalPetrochemicals and include, but are not limited to, grades M3551,M3282MZ, M7672, 1251, 1471, 1571, and 1751.

“Metallocene polypropylene-ethylene copolymer” is metallocenesyndiotactic, metallocene atactic, and metallocene isotacticpolypropylene with random ethylene units. Commercially availableexamples include, but are not limited to, Lumicene® MR10MX0 andLumicene® MR60MC2 from Total Petrochemicals and Purell® SM170G fromLyondellBasell.

“Metallocene polypropylene olefin block copolymer” is a polypropylenewith alternating crystallizable hard “blocks” and amorphous soft“blocks” that are not randomly distributed—that is, with a controlledblock sequence. An example of “metallocene polypropylene olefin blockcopolymer” includes, but is not limited to, the INTUNE™ product linefrom the Dow Chemical Company.

“Polypropylene based polyolefin plastomer” (POP) and “polypropylenebased polyolefin elastoplastomer” are both metallocene andnon-metallocene propylene based copolymers with plastomeric andelastoplastomeric properties. Non-limiting examples are thosecommercially available under the trade name VERSIFY™ (metallocene) fromthe Dow Chemical Company, VISTAMAXX™ (metallocene) from ExxonMobil, andKOATTRO™ (non-metallocene) from LyondellBasell (a butene-1 based line ofplastomeric polymers—certain grades are butene-1 homopolymer based andothers are polypropylene-butene-1 copolymer based materials).

“Polypropylene based polyolefin elastomer” (POE) is both metallocene andnon-metallocene propylene based copolymer with elastomeric properties.Non-limiting examples of propylene based polyolefin elastomers are thosepolymers commercially available under the trade names THERMORUN™ andZELAS™ (non-metallocene) from Mitsubishi Chemical Corporation, ADFLEX™and SOFTELL™ (both non-metallocene) from LyondellBasell, VERSIFY™(metallocene) from the Dow Chemical Company, and VISTAMAXX™(metallocene) from ExxonMobil.

“Polypropylene based thermoplastic polyolefin blend” (TPO) ispolypropylene, polypropylene-ethylene copolymer, metallocenehomopolypropylene, and metallocene polypropylene-ethylene copolymer,which have ethylene-propylene copolymer rubber in amounts great enoughto give the thermoplastic polyolefin blend (TPO) plastomeric,elastoplastomeric or elastomeric properties. Non-limiting examples ofpolypropylene based polyolefin blend polymers are those polymer blendscommercially available under the trade names EXCELINK™ from JSRCorporation, THERMORUN™ and ZELAS™ from Mitsubishi Chemical Corporation,FERROFLEX™ and RxLOY™ from Ferro Corporation, and TELCAR™ from TeknorApex Company.

“Polypropylene based thermoplastic elastomer blend” (TPE) ispolypropylene, polypropylene-ethylene copolymer, metallocenehomopolypropylene, and metallocene polypropylene-ethylene copolymer,which have diblock or multiblock thermoplastic rubber modifiers (SEBS,SEPS, SEEPS, SEP, SERC, CEBC, HSB and the like) in amounts great enoughto give the thermoplastic elastomer blend (TPE) plastomeric,elastoplastomeric, or elastomeric properties. Non-limiting examples ofpolypropylene based thermoplastic elastomer blend polymers are thosepolymer blends commercially available under the trade name DYNAFLEX® andVERSAFLEX® from GLS Corporation, MONPRENE® and TEKRON® from Teknor ApexCompany and DURAGRIP® from Advanced Polymers Alloys (a division of FerroCorporation).

All of the above polypropylenes may be grafted with maleic anhydride.Non-limiting examples are ADMER® QF500A and ADMER® QF551A from MitsuiChemicals. It should be noted that most commercial anhydride-graftedpolypropylenes also contain rubber.

The term “polyethylene” includes, but is not limited to, LDPE, LLDPE,VLDPE, VLLDPE, HDPE, polyethylene-propylene copolymer, metallocenepolyethylene, metallocene ethylene-propylene copolymer, and metallocenepolyethylene olefin block copolymer (with a controlled block sequence).

“Metallocene polyethylene” is metallocene based polyethylene withproperties ranging from non-elastic to elastomeric. Non-limitingexamples of metallocene polyethylene are commercially available underthe trade name ENGAGE™ from Dow Chemical Company, ENABLE™ and EXCEED™from ExxonMobil, and EXACT™ from Borealis.

“VLDPE” and “VLLDPE” are very low density polyethylene and very lineardensity low density polyethylene containing an elastic or softeningcomponent, typically α-olefins. Non-limiting examples of VLDPE andVLLDPE are commercially available under the tradename FLEXOMER™ from theDow Chemical Company and particular grades of STAMYLEX™ from Borealis.

“Metallocene polyethylene olefin block copolymer” is a polyethylene withalternating crystallizable hard “blocks” and amorphous soft “blocks”that are not randomly distributed—that is, with a controlled blocksequence. An example of “metallocene polyethylene olefin blockcopolymer” includes, but is not limited to, the INFUSE™ product linefrom the Dow Chemical Company.

All of the above polyethylenes may be grafted with maleic anhydride.Non-limiting commercially available examples are ADMER® NF539A fromMitsui Chemicals, BYNEL® 4104 from DuPont, and OREVAC® 18360 fromArkema. It should be noted that most commercial anhydride-graftedpolyethylenes also contain rubber.

These polyethylenes may also be copolymers and terpolymers containingacetate and/or ester groups. The comonomer groups include, but are notlimited to, vinyl acetate, methyl acrylate, ethyl acrylate, butylacrylate, glycidyl methacrylate, and acrylic acid. Non-limiting examplesare commercially available under the tradename BYNEL®, ELVAX® andELVALOY® from DuPont; EVATANE®, LOTADER®, and LOTRYL® from Arkema;ESCORENE™, ESCOR™, and OPTEMA™ from ExxonMobil.

These polyethylenes may also be copolymer and terpolymer ionomerscontaining acetate and/or ester groups. A common comonomer group is, butis not limited to, methacrylic acid. Non-limiting examples arecommercially available under the tradename SURLYN® from DuPont; IOTEK™from ExxonMobil, and AMPLIFY™ IO from Dow Chemical Company.

The polymer component of the recycled polyolefin may also contain EVOHand/or PVOH (“PVA”). “EVOH” is a copolymer of ethylene and vinylalcohol. Non-limiting examples are commercially available under thetradename EVAL™ and EXCEVAL™ from Kuraray and SOARNOL™ from NipponGohsei. “PVOH” is a polyvinyl alcohol. Non-limiting examples arecommercially available under the tradename ELVANOL® from DuPont andPOVAL®, MOWIOL®, and MOWIFLEX® from Kuraray.

The recycled polyolefin foam material used to form the recycled layer(s)includes, but is not limited to, cryogenically pulverized factory scrap,crosslinked foam including polypropylene foams, polyethylene foams, orpolypropylene/polyethylene blended foams. When the foam composition fedinto the extruder to form the recycled layer(s) includes recycledpolyolefin foam material, the foam compositions can include about 5 toabout 50 wt. % recycled polyolefin foam material, preferably from about10 to about 45 wt. %, and more preferably from about 15 to about 40 wt.%. In addition, these recycled polyolefin foam material foamcompositions can include about 50 to about 95 wt. %, preferably about 55to about 90 wt. %, and more preferably about 60 to about 85 wt. %polypropylene, polyethylene, or combinations thereof.

Cryogenic pulverizing (also known as cryogenic grinding) is a methodthat can be employed to effectively and efficiently reduce heatsensitive, oxidizable, and/or “tough-to-mill” materials into a finepowder. A crosslinked, polyolefin foam is an example of one suchmaterial that is not well suited for ambient milling systems. In thecryogenic pulverizing process, a cryogenic liquid such as nitrogen orcarbon dioxide can be used to cool the material prior to and/or duringmilling to help prevent its melting and/or achieve embrittlement.Cryogenically pulverized factory scrap crosslinked foams (includingpolypropylene foams, polyethylene foams, and polypropylene/polyethyleneblended foams) are commercially available from commercial cryogenicpulverizers in various particle sizes and distributions.

Grinding mills typically contain a sieve near the discharge chute toensure that the material being pulverized can be reduced to at least amaximum desired particle size. The milling sieve can be at least a 3.5U.S. Standard mesh, preferably at least a 6 U.S. Standard mesh, and morepreferably at least a 30 U.S. Standard mesh. It can be preferred thatthe recycled foam material pieces be reduced in size to pass thru atleast a 3.5 U.S. Standard mesh (5.6 mm opening), preferably at least a 6U.S. Standard mesh (3.35 mm opening), and more preferably at least a 30U.S. Standard mesh (0.600 mm opening).

A non-limiting example of finely pulverized recycled factory scrapcrosslinked polypropylene, polyethylene, and polypropylene/polyethyleneblended foam is that produced from Midwest Elastomers, Inc. (Wapakoneta,Ohio). Such recycled foam from Midwest Elastomers can be pulverized witha 30 U.S. Standard mesh sieve installed near the discharge chute.

The recycled polyolefin foam material can also include foam materialthat already included recycled polyolefin material. As such, therecycled polyolefin foam material can be re-recycled polyolefinmaterial. For example, the recycled polyolefin foam material may alreadycontain recycled contents of metallized polyolefin material and/orcryogenically pulverized factor scrap crosslinked foams. In addition,the recycled polyolefin foam material can include foams derived fromrecycled metallized polyolefin material as disclosed in U.S. applicationSer. No. 14/144,986, which is hereby incorporated by reference in itsentirety.

The foam compositions fed into the extruders to form the various foamlayers can include at least one polypropylene having a melt flow indexfrom about 0.1 to about 25 grams per 10 minutes at 230° C. and/or atleast one polyethylene having a melt flow index from about 0.1 to about25 grams per 10 minutes at 190° C. In some embodiments, the melt flowindex of the polypropylene(s) and/or polyethylene(s) can preferably befrom about 0.3 to about 20 grams per 10 minutes at 230° C. and at 190°C., respectively, and more preferably from about 0.5 to about 15 gramsper 10 minutes at 230° C. and at 190° C., respectively.

The “melt flow index” (MFI) value for a polymer can be defined andmeasured according to ASTM D1238 at 230° C. for polypropylenes andpolypropylene based materials and at 190° C. for polyethylenes andpolyethylene based materials using a 2.16 kg plunger for 10 minutes. Thetest time may be reduced for relatively high melt flow resins.

The MFI provides a measure of flow characteristics of a polymer and isan indication of the molecular weight and processability of a polymermaterial. If the MFI values are too high, which corresponds to a lowviscosity, extrusion according to the present disclosure may not besatisfactorily carried out. Problems associated with MFI values that aretoo high include low pressures during extrusion, problems setting thethickness profile, uneven cooling profile due to low melt viscosity,poor melt strength, machine problems, or a combination thereof. Problemswith MFI values that are too low include high pressures during meltprocessing, sheet quality and profile problems, and higher extrusiontemperatures which cause a risk of foaming agent decomposition andactivation.

The above MFI ranges are also important for foaming processes becausethey reflect the viscosity of the material and the viscosity has aneffect on the foaming. Without being bound by any theory, it is believedthere are several reasons why particular MFI values are more effectivethan others. A lower MFI material may improve some physical propertiesas the molecular chain length is greater, creating more energy neededfor chains to flow when a stress is applied. Also, the longer themolecular chain (MW), the more crystal entities the chain cancrystallize thus providing more strength through intermolecular ties.However, at too low an MFI, the viscosity becomes too high. On the otherhand, polymers with higher MFI values have shorter chains. Therefore, ina given volume of a material with higher MFI values, there are morechain ends on a microscopic level relative to polymers having a lowerMFI, which can rotate and create free volume due to the space needed forsuch rotation (e.g., rotation occurring above the T_(g), or glasstransition temperature of the polymer). This increases the free volumeand enables an easy flow under stress forces.

These polypropylene(s) and/or polyethylene(s) with specific MFI valueswhich can be used in forming any of the layers of the foam multilayerstructure include the same types described earlier. That is, thepolypropylene includes, but is not limited to, polypropylene, impactmodified polypropylene, polypropylene-ethylene copolymer, impactmodified polypropylene-ethylene copolymer, metallocene polypropylene,metallocene polypropylene-ethylene copolymer, metallocene polypropyleneolefin block copolymer (with a controlled block sequence), polypropylenebased polyolefin plastomer, polypropylene based polyolefinelasto-plastomer, polypropylene based polyolefin elastomer,polypropylene based thermoplastic polyolefin blend and polypropylenebased thermoplastic elastomeric blend. Furthermore, the polypropylenesmay be grafted with maleic anhydride. In addition, the polyethyleneincludes, but is not limited to, LDPE, LLDPE, VLDPE, VLLDPE, HDPE,polyethylene-propylene copolymer, metallocene polyethylene, metalloceneethylene-propylene copolymer, and metallocene polyethylene olefin blockcopolymer (with a controlled block sequence), any of which may containgrafted compatibilizers or copolymers that contain acetate and/or estergroups. As discussed previously, these polyethylenes may be grafted withmaleic anhydride. These polyethylenes may also be copolymers andterpolymers containing acetate and/or ester groups and may be copolymerand terpolymer ionomers containing acetate and/or ester groups.

When relatively large or thick pieces of metal (in relation to the foamcell size) are present in the recycled layer of the multilayer foamstructure, undesirable “voids” and “large cells” may occur. Thus,including polypropylene and/or polyethylene with grafted compatibilizersor copolymers that contain acetate and/or ester groups as ingredientsmay be required to prevent the formation of these undesirable “voids”and “large cells”.

In addition, the foam compositions fed into the extruder may alsocontain further additives compatible with producing the disclosedmultilayer foam structures. Common additives include, but are notlimited to, organic peroxides, antioxidants, extrusion processing aids,other lubricants, thermal stabilizers, colorants, flame retardants,antistatic agents, nucleating agents, plasticizers, antimicrobials,antifungals, light stabilizers, UV absorbents, anti-blocking agents,fillers, deodorizers, thickeners, cell size stabilizers, metaldeactivators, and combinations thereof.

Regardless of how all the ingredients are fed into the extruders, theshearing force and mixing within an extruder processing recycledpolyolefin material should be sufficient to produce a homogenous layer(in as much as the recycled polyolefin material being fed into theextruder is homogenous). A co-rotating twin screw extruder can providesufficient shearing force and mixing thru the extruder barrel to extrudea layer with uniform properties.

Specific energy is an indicator of how much work is being applied duringthe extrusion of the ingredients and how intensive the extrusion processis. Specific energy can be defined as the energy applied to a materialbeing processed by the extruder, normalized to a per kilogram basis. Thespecific energy can be quantified in units of kilowatts of appliedenergy per total material fed in kilograms per hour. Specific energy canbe calculated according to the formula:

${{{Specific}\mspace{14mu}{Energy}} = \frac{{KW}\mspace{14mu}({applied})}{{feedrate}\mspace{14mu}\left( \frac{kg}{hr} \right)}},{where}$${{KW}\mspace{14mu}({applied})} = \frac{\begin{matrix}{{KW}\mspace{14mu}\left( {{motor}\mspace{14mu}{rating}} \right)*} \\{\left( {\%\mspace{14mu}{torque}\mspace{14mu}{from}\mspace{14mu}{maximum}\mspace{14mu}{allowable}} \right)*} \\{{RPM}\left( {{actual}\mspace{14mu}{running}\mspace{14mu}{RPM}} \right)}\end{matrix}}{\begin{matrix}{{Max}\mspace{14mu}{{RPM}\left( {{capability}\mspace{14mu}{of}\mspace{14mu}{extruder}} \right)}*} \\{0.97\left( {{gearbox}\mspace{14mu}{efficiency}} \right)}\end{matrix}}$

Specific energy can be used to quantify the amount of shearing andmixing of the ingredients within an extruder. The extruders used for thepresent invention can be capable of producing a specific energy of atleast 0.090 kW·hr/kg, preferably at least 0.105 kW·hr/kg, and morepreferably at least 0.120 kW·hr/kg.

The extrusion temperature for each layer of the multilayer structurescan be at least 10° C. below the thermal decomposition initiationtemperature of the chemical foaming (i.e., “blowing”) agent. If theextrusion temperature exceeds the thermal decomposition temperature ofthe foaming agent, then the foaming agent will decompose, resulting inundesirable “prefoaming.”

The foam compositions can include a variety of different chemicalfoaming agents. Examples of chemical foaming agents include, but are notlimited to, azo compounds, hydrazine compounds, carbazides, tetrazoles,nitroso compounds, and carbonates. In addition, a chemical foaming agentmay be employed alone or in any combination. Generally, the amount ofthe chemical foaming agent can be about the same in the various layers.For example, if one layer has significantly more PPHR of a chemicalfoaming agent than another layer (assuming the same chemical foamingagent), then the layer that is foaming less could hinder the expansionof the layer that is foaming more. Thus, problems with the multilayerstructure curling, buckling, and/or folding onto itself may occur as themultilayer structure is heated and foamed.

One chemical foaming agent that can be used in some embodiments isazodicarbonamide (“ADCA”). The amount of ADCA in a foam layercomposition can be less than or equal to about 40% PPHR. ADCA's thermaldecomposition typically occurs at temperatures between about 190 to 230°C. In order to prevent ADCA from thermally decomposing in the extruder,extruding temperature can be maintained at or below 190° C. Anotherchemical foaming agent that can be used in some embodiments isp-toluenesulfonyl hydrazide (“TSH”). The amount of TSH in a foam layercomposition can be less than or equal to 77% PPHR. Another chemicalfoaming agent that can be used in some embodiments is p-toluenesulfonylsemicarbazide (“TSS”). The amount of TSS in a foam layer composition canbe less than or equal to 63% PPHR. The amount of chemical foaming agentcan depend on the unfoamed sheet thickness, the desired foam thickness,desired foam density, materials being extruded, crosslinking percentage,type of chemical foaming agent (different foaming agents cansignificantly generate different quantities of gas), among others.However, the amount of foaming agent in each layer should be chosen inorder for the foaming of each layer to be relatively equal.

If the difference between the decomposition temperature of the thermallydecomposable foaming agent and the melting point of the polymer with thehighest melting point is high, then a catalyst for foaming agentdecomposition may be used. Exemplary catalysts include, but are notlimited to, zinc oxide, magnesium oxide, calcium stearate, glycerin, andurea.

The lower temperature limit for extrusion can be that of the polymerwith the highest melting point. If the extrusion temperature drops belowthe melting temperature of the polymer with the highest melting point,then undesirable “unmelts” can appear in the structure. Upon foaming,the extruded layer that was extruded below this lower temperature limitcan exhibit uneven thickness, a non-uniform cell structure, pockets ofcell collapse, and other undesirable attributes.

Extruding an unfoamed multilayer sheet (as described in the presentapplication) is different than extruding a foamed multilayer sheet,commonly referred to as “extrusion foaming.” Extrusion foaming can beperformed with a physical foaming agent, a chemical foaming agent, or acombination thereof. Examples of physical foaming agents are inorganicand organic gases (e.g., nitrogen, carbon dioxide, pentane, butane,etc.) that can be injected under high pressure directly into the polymermelt. These gases can nucleate and expand as the polyolefin melt exitsthe extrusion die to create the foamed polymer. Examples of chemicalfoaming agents (e.g., those previously described in the disclosure) aresolids that can decompose exothermally or endothermally upon adecomposition temperature to produce gases. Typical gases generated fromchemical foaming agents include nitrogen, carbon dioxide, carbonmonoxide, and ammonia among others. In order to extrusion foam using achemical foaming agent, the chemical foaming agent can be dispersed inthe polyolefin melt and the melt can be heated to above thedecomposition temperature of the chemical foaming agent while still inthe extruder and die. As such, the foamed polymer can be made as thepolyolefin melt exits the extrusion die.

Regardless of whether the foaming agent is a physical foaming agent,chemical foaming agent, or a combination thereof, typical extrusionfoaming generates polyolefin foam structures with surfaces that aresignificantly rougher than equivalent foam structures produced by thedisclosed method of first coextruding an unfoamed, multilayer sheet,wherein the foaming occurs post-extrusion. Rougher surfaces of extrusionfoamed structures are generally caused by larger sized cells whencompared to foams produced by the disclosed methods of first coextrudingan unfoamed multilayer sheet. Although the cell size and sizedistribution of a foam structure may not be critical in some commercialapplications, since surface roughness is a function of cell size, foamswith larger cells may be less desirable than foam structures withsmaller cells for applications requiring a smooth foam surface.

As stated above, the surface profile for foam structures is critical inmany applications and therefore extrusion foamed structures may not bedesirable for these applications. Instead, these applications require asmooth foam structure surface to obtain desired properties such as easeof lamination to a film, fabric, fiber layer, and/or leather; percentagecontact in the lamination; and visual aesthetics among others. Acomparison between the surface roughness of an extrusion foamed sheetand a non-extrusion foamed sheet produced by the methods describedherein can be found in the Examples section below. The mean surfaceroughness for the foams produced by the methods described herein can beless than about 80 μm, less than about 70 μm, less than about 50 μm,less than about 40 μm, less than about 30 μm, less than about 25 μm,less than about 20 μm, less than about 15 μm, and less than about 10 μm.The maximum height (height between the highest peak and the deepestvalley) of the surface of the foams produced by the methods describedherein can be less than about 700 μm, less than about 600 μm, less thanabout 300 μm, less than about 250 μm, less than about 200 μm, less thanabout 150 μm, and less than 100 μm.

The thickness of an unfoamed, co-extruded multilayer structure can beabout 0.1 to about 30 mm, preferably from about 0.2 to about 25 mm, morepreferably from about 0.3 to about 20 mm, and even more preferably fromabout 0.4 to about 15 mm. In addition, the thickness of any individuallayer including the recycled layer(s) and non-recycled layer(s) in theunfoamed, co-extruded multilayer structure can be at least about 0.05mm, preferably at least about 0.1 mm, more preferably at least about0.15 mm, and even more preferably at least about 0.2 mm.

In embodiments where a layer(s) of the multilayer structure is notintended to be foamed (e.g., wherein a layer is a “skin” or “film”layer), the non-foaming layer(s) can be thin and easily pliable whenmelted so as to not significantly hinder the expansion of the foamlayer(s) during the foaming process. The physical properties of thenon-foaming layer(s) that can hinder the expansion of the foam layer(s)include, but are not limited to, the non-foaming layer's thickness,flexibility, melt strength, and crosslinking percentage. Similarly, thethickness, flexibility, melt strength, and crosslinking percentage ofthe foam layer(s) as well as the ultimate thickness and density of thefoam layer(s) can also affect whether the non-foaming layer(s) inhibitsthe expansion of the foam layer(s).

In general, the non-foaming layer(s)'s thickness can preferably be nomore than about 20% of the overall coextruded unfoamed structure'sthickness. When the non-foaming layer(s)'s thickness is greater thanabout 20% of the overall thickness of the coextruded, unfoamedstructure, problems with the multilayer structure curling, buckling,and/or folding onto itself may occur as the multilayer structure isheated and foamed. In contrast, the non-foaming layer(s)'s thickness isnot limited to how thin it can be in relation to the overall unfoamed,coextruded multilayer structure. For example, the non-foaming layer(s)can be as thin as about 0.1 μm (i.e., the typical thickness of a thintie layer used in multilayer flexible packaging and barrier films).

After the co-extruded multilayer structure has been produced by theextruders, the coextruded structure can be subjected to irradiation withionizing radiation at a given exposure to crosslink the composition ofthe coextruded structure, thereby obtaining an irradiated, crosslinked,multilayer structure. Ionizing radiation can often be unable to producea sufficient degree of crosslinking on polypropylene(s), polypropylenebased materials, some polyethylene(s), and some polyethylene basedmaterials. Thus, a crosslinking promoter can typically be added to thefoam compositions that are fed into the extruders to promotecrosslinking. Polymers crosslinked by ionizing radiation are commonlyreferred to as “physically crosslinked.”

Physical crosslinking differs from chemical crosslinking. In chemicalcrosslinking, the crosslinks can be generated with crosslinkingpromoters, but without the use of ionizing radiation. Chemicalcrosslinking can typically include using either peroxides, silanes, orvinylsilanes. During peroxide crosslinking processes, the crosslinkingtypically occurs in the extrusion die. In contrast, for silane andvinylsilane crosslinking processes, the crosslinking typically occurspost extrusion during a secondary operation where the crosslinking ofthe extruded material can be accelerated with heat and moisture.

Regardless of the chemical crosslinking process, chemically crosslinkedfoam structures typically exhibit surfaces that are significantlyrougher than equivalent foam structures produced by the disclosed methodof physical crosslinking. Rougher surfaces of chemically crosslinkedfoam structures are generally caused by larger sized cells when comparedto foams produced by the disclosed methods of using physicalcrosslinking. Although the cell size and size distribution of a foamstructure may not be critical in some commercial applications, sincesurface roughness is a function of cell size, foams with larger cellsmay be less desirable than foam structures with smaller cells forapplications requiring a smooth foam surface.

As stated above, the surface profile for foam structures is critical inmany applications and therefore chemically crosslinked structures arenot desirable for these applications. Instead, these applicationsrequire a smooth foam structure surface to obtain desired propertiessuch as ease of lamination to a film, fabric, fiber layer, and/orleather; percentage contact in the lamination; and visual aestheticsamong others. A comparison between the surface roughness of a chemicallycrosslinked sheet and a physically crosslinked sheet produced by themethods described herein can be found in the Examples section below.

Examples of ionizing radiation include, but are not limited to, alpharays, beta rays, gamma rays, and electron beams. Among them, an electronbeam having uniform energy can preferably be used to prepare thecrosslinked, multilayer structures. Exposure time, frequency ofirradiation, and acceleration voltage upon irradiation with an electronbeam can vary widely depending on the intended crosslinking degree andthe thickness of the coextruded, multilayer structure. However, theionizing radiation should generally be in the range of from about 10 toabout 500 kGy, preferably from about 20 to about 300 kGy, and morepreferably from about 20 to about 200 kGy. If the exposure is too low,then cell stability may not be maintained upon foaming. If the exposureis too high, the moldability of the resulting multilayer foam structuremay be poor. (Moldability can be a desirable property when themultilayer foam structure is used in thermoforming applications.) Also,the unfoamed multilayer structure may be softened by exothermic heatrelease upon exposure to the electron beam radiation such that thestructure can deform when the exposure is too high. In addition, thepolymer components may also be degraded from excessive polymer chainscission.

The coextruded, unfoamed multilayer structure may be irradiated up to 4separate times, preferably no more than twice, and more preferably onlyonce. If the irradiation frequency is more than about 4 times, thepolymer components may suffer degradation so that upon foaming, forexample, uniform cells will not be created in the resulting foam layers.

When the thickness of the coextruded multilayer structure is greaterthan about 4 mm, irradiating each primary surface of the multilayerprofile with an ionized radiation can be preferred to make the degree ofcrosslinking of the primary surface(s) and the inner layer(s) moreuniform.

Irradiation with an electron beam provides an advantage in thatcoextruded structures having various thicknesses can be effectivelycrosslinked by controlling the acceleration voltage of the electrons.The acceleration voltage can generally be in the range of from about 200to about 1500 kV, preferably from about 400 to about 1200 kV, and morepreferably about 600 to about 1000 kV. If the acceleration voltage isless than about 200 kV, then the radiation may not reach the innerportion of the coextruded structure. As a result, the cells in the innerportion can be coarse and uneven on foaming. Additionally, accelerationvoltage that is too low for a given thickness profile may cause arcing,resulting in “pinholes” or “tunnels” in the foamed multilayer structure.On the other hand, if the acceleration voltage is greater than about1500 kV, then the polymers may degrade.

Regardless of the type of ionizing radiation selected, crosslinking canbe performed so that the composition of the coextruded structure can becrosslinked about 20 to about 75%, preferably about 30 to about 60%, asmeasured by the “Toray Gel Fraction Percentage Method.”

According to the “Toray Gel Fraction Percentage Method,” tetralinsolvent is used to dissolve non-crosslinked components in a composition.In principle, the non-crosslinked material is dissolved in tetralin andthe crosslinking degree is expressed as the weight percentage ofcrosslinked material in the entire composition.

The apparatus used to determine the percent of polymer crosslinkingincludes: 100 mesh (0.0045 inch wire diameter); Type 304 stainless steelbags; numbered wires and clips; a Miyamoto thermostatic oil bathapparatus; an analytical balance; a fume hood; a gas burner; a hightemperature oven; an anti-static gun; and three 3.5 liter wide mouthstainless steel containers with lids. Reagents and materials usedinclude tetralin high molecular weight solvent, acetone, and siliconeoil. Specifically, an empty wire mesh bag is weighed and the weightrecorded. For each sample, about 100 milligrams±about 5 milligrams ofsample is weighed out and transferred to the wire mesh bag. The weightof the wire mesh bag and the sample, typically in the form of foamcuttings, is recorded. Each bag is attached to the corresponding numberwire and clips. When the solvent temperature reaches 130° C., the bundle(bag and sample) is immersed in the solvent. The samples are shaken upand down about 5 or 6 times to loosen any air bubbles and fully wet thesamples. The samples are attached to an agitator and agitated for three(3) hours so that the solvent can dissolve the foam. The samples arethen cooled in a fume hood. The samples are washed by shaking up anddown about 7 or 8 times in a container of primary acetone. The samplesare washed a second time in a second acetone wash. The washed samplesare washed once more in a third container of fresh acetone as above. Thesamples are then hung in a fume hood to evaporate the acetone for about1 to about 5 minutes. The samples are then dried in a drying oven forabout 1 hour at 120° C. The samples are cooled for a minimum of about 15minutes. The wire mesh bag is weighed on an analytical balance and theweight is recorded.

Crosslinking can then be calculated using the formula 100*(C−A)/(B−A),where A=empty wire mesh bag weight; B=wire bag weight+foam sample beforeimmersion in tetralin; and C=wire bag weight+dissolved sample afterimmersion in tetralin.

Suitable crosslinking agents include, but are not limited to,commercially available difunctional, trifunctional, tetrafunctional,pentafunctional, and higher functionality monomers. Such crosslinkingmonomers are available in liquid, solid, pellet, and powder forms.Examples include, but are not limited to, acrylates or methacrylatessuch as 1,6-hexanediol diacrylate, 1,6-hexanediol dimethacrylate,ethylene glycol diacrylate, ethylene glycol dimethacrylate, trimethylolpropane trimethacrylate, tetramethylol methane triacrylate,1,9-nonanediol dimethacrylate and 1,10-decanediol dimethacrylate; allylesters of carboxylic acid (such as trimellitic acid triallyl ester,pyromellitic acid triallyl ester, and oxalic acid diallyl ester); allylesters of cyanulic acid or isocyanulic acid such as triallyl cyanurateand triallyl isocyanurate; maleimide compounds such as N-phenylmaleimide and N,N′-m-phenylene bismaleimide; compounds having at leasttwo tribonds such as phthalic acid dipropagyl and maleic aciddipropagyl; and divinylbenzene. Additionally, such crosslinking agentsmay be used alone or in any combination. The amount of crosslinkingagent used in a layer's composition can vary based on the molecularweight, functionality, and crosslinking efficiency of the crosslinkingagent and the ionizing radiation dosage, among others. Divinylbenzene(DVB), a difunctional liquid crosslinking monomer, can be used as acrosslinking agent in the present invention and added to an extruder ata level no greater than about 4% PPHR, and preferably about 2% to about3.5% PPHR. Some polymers more readily crosslink more than others. Thus,layers containing polymers more apt to crosslink may have lesscrosslinking agent, than layers with polymers less apt to crosslink. Insome embodiments, a layer can be purposefully more crosslinked thananother layer, which can require adding more crosslinking agent intothat layer to facilitate more crosslinking.

Crosslinks may be generated using a variety of different techniques andcan be formed both intermolecularly, between different polymermolecules, and intramolecularly, between portions of a single polymermolecule. Such techniques include, but are not limited to, providingcrosslinking agents which are separate from a polymer chain andproviding polymer chains which incorporate a crosslinking agentcontaining a functional group which can form a crosslink or be activatedto form a crosslink.

After irradiating the extruded structure, foaming may be accomplished byheating the crosslinked multilayer structure to a temperature higherthan the decomposition temperature of the thermally decomposable foamingagent. For the thermally decomposable foaming agent azodicarbonamide,the foaming can be performed at about 200 to about 260° C., preferablyabout 220 to about 240° C., in a continuous process. A continuousfoaming process can be preferred over a batch process for production ofa continuous foam sheet.

The foaming can typically be conducted by heating the crosslinkedmultilayer structure with molten salt, radiant heaters, vertical hot airoven, horizontal hot air oven, microwave energy, or a combination ofthese methods. The foaming may also be conducted in an impregnationprocess using, for example, nitrogen in an autoclave, followed by a freefoaming via molten salt, radiant heaters, vertical hot air oven,horizontal hot air oven, microwave energy, or a combination of thesemethods. A preferred combination of molten salt and radiant heaters canbe used to heat the crosslinked multilayer structure. Specifically, theside of the irradiated, extruded structure that is not in contact withthe molten salt can be heated via radiant heaters.

Optionally, before foaming, the crosslinked structure can be softenedwith preheating. This can help stabilize the expansion of the structureupon foaming.

The density of the multilayer foam structure can be defined and measuredusing section or “overall” density, rather than a “core” density, asmeasured by JIS K6767. The multilayer foam structure produced using theabove described method can yield foams with a section, or “overall”density of about 20 to about 250 kg/m³, preferably about 30 kg/m³ toabout 125 kg/m³. The section density can be controlled by the amount offoaming agent and the thickness of the coextruded structure. If thedensity of the structure is less than about 20 kg/m³, then the structuremay not foam efficiently due to a large amount of chemical foaming agentneeded to attain the density. Additionally, if the density of thestructure is less than about 20 kg/m³, then the expansion of thestructure during the foaming step may become increasingly difficult tocontrol. Furthermore, if the density of the multilayer foam structure isless than 20 kg/m³, then the foam structure may become increasinglyprone to cell collapse. Thus, it can be difficult to produce amultilayer foam structure of uniform section density and thickness (withor without recycled material) at a density less than about 20 kg/m³.

The multilayer foam structure is not limited to a section density ofabout 250 kg/m³. A foam of about at least 350 kg/m³, about at least 450kg/m³, or about at least 550 kg/m³ may also be produced. However, it canbe preferred that the multilayer foam structure have a density of lessthan about 250 kg/m³ since greater densities may generally be costprohibitive when compared to other materials which can be used in agiven application.

The various foamed layers (with or without recycled polyolefin material)in the multilayer foam structures can have similar densities. Thesedensities can be determined and adjusted by the amount of the chemicalfoaming agent(s), type(s) of the chemical foaming agent, thickness ofeach of the coextruded unfoamed layer(s), and/or the overall thicknessof the coextruded unfoamed multilayer structure. When the individualfoamed layers have significantly different densities from each other,problems with the multilayer foam structure curling, buckling, andfolding onto itself may occur as the multilayer structure is heated andfoamed. The densities of the foamed layers can have densities withinabout 15% of each other, preferably within about 10% of each other, andmore preferably within about 5% of each other.

The multilayer foam structures produced using the above method may haveclosed cells. Preferably, at least 90% of the cells have undamaged cellwalls, preferably at least 95%, and more preferably more than 98%. Theaverage cell size can be from about 0.05 to about 1.0 mm, and preferablyfrom about 0.1 to about 0.7 mm. If the average cell size is lower thanabout 0.05 mm, then the density of the multilayer foam structure cantypically be greater than 250 kg/m³. If the average cell size is largerthan 1 mm, the foam may have an uneven surface. There is also apossibility of the foam structure being undesirably torn if thepopulation of cells in the foam does not have the preferred average cellsize. This can occur when the foam structure is stretched or portions ofit are subjected to a secondary process. The cell size in the multilayerfoam structure may have a bimodal distribution representing a populationof cells in the core of the foam structure which are relatively roundand a population of cells in the skin near the surfaces of the foamstructure which are relatively flat, thin, and/or oblong.

The thickness of the multilayer foam structure can be about 0.2 mm toabout 50 mm, preferably from about 0.4 mm to about 40 mm, morepreferably from about 0.6 mm to about 30 mm, and even more preferablyfrom about 0.8 mm to about 20 mm. If the thickness is less than about0.2 mm, then foaming may not be efficient due to significant gas lossfrom the primary surfaces. If the thickness is greater than about 50 mm,expansion during the foaming step may become increasingly difficult tocontrol. Thus, it can be increasingly more difficult to produce amultilayer foam structure (with or without recycled polyolefin material)with uniform section density and thickness.

The desired thickness can also be obtained by a secondary process suchas slicing, skiving, or bonding. Slicing, skiving, or bonding canproduce a thickness range of about 0.1 mm to about 100 mm.

In embodiments where a layer(s) of the multilayer structure is notintended to be foamed, the thickness of the non-foaming layer(s) may bereduced upon foaming the multilayer structure. This can be from thefoaming layer(s) expanding and consequently stretching the non-foaminglayer(s). Thus, for example, if the multilayer structure expands totwice its original area, the non-foaming layer(s) thickness can beexpected to be about halved. Furthermore, if the multilayer structureexpands to four times its original area, the non-foaming layer(s) can beexpected to be reduced to about one-quarter of its original thickness.

The disclosed multilayer foam structures can be used in a variety ofapplications. One such application is foam tapes and gasketing. Closedcell foam tape is commonly used in areas such as window glazing, wherestrips of foam tape are placed between two window panes to seal the airbetween the glass. This improves the thermal insulation property of thewindow. The foam also acts as a cushion for the glass panes from theeffects of thermal expansion and contraction of the building and windowframe from daily and seasonal temperature changes. Likewise, closed cellfoam gaskets are commonly used for sealing and cushioning. Handheldelectronic devices and household appliances are two examples that maycontain foam gaskets. A soft, flexible foam structure is usually suitedas a tape or gasket.

When the multilayer foam structure is to be used as a tape or gasket, apressure sensitive adhesive layer may be disposed on at least a portionof one or both major surfaces. Any pressure sensitive adhesive known inthe art may be used. Examples of such pressure sensitive adhesivesinclude, but are not limited to, acrylic polymers, polyurethanes,thermoplastic elastomers, block copolymers, polyolefins, silicones,rubber based adhesives, copolymers of ethylhexylacrylate and acrylicacid, copolymers of isooctyl acrylate and acrylic acid, blends ofacrylic adhesives and rubber based adhesives as well as combinations ofthe foregoing.

The multilayer foam structures can also be thermoformed. To thermoformthe multilayer foam structure, the foam can be heated to the meltingpoint of the polyolefin blend for all the layers in the multilayer foamstructure. If any layer has immiscible polymers, the multilayer foamstructure may exhibit more than one melting point. In this case, themultilayer foam structure can typically be thermoformed when the foam isheated to a temperature midway between the multilayer foam composition'slowest melting point and highest melting point. In addition, themultilayer foam structure can be thermoformed onto a substrate such as ahard polypropylene, ABS, or wood fiber composite. Preferably, themultilayer foam structure can be thermoformed onto the substrate suchthat a side of a non-recycled foam layer of the multilayer foam isapplied to the substrate. The substrate itself can also be thermoformedat the same time as the multilayer foam structure. In addition, thesubstrate can be applied to a side (i.e., surface) of a non-recycledfoam layer of the multilayer foam.

One example of a thermoformed article is an automobile air duct. Aclosed cell foam structure can be particularly suited for thisapplication due to its lower weight (when compared to solid plastic),its insulating properties that help maintain the temperature of the airflowing thru the duct, and its resistance to vibration (versus solidplastic). Thus, a firm multilayer foam structure can be suitable for anautomobile air duct.

In some embodiments, the multilayer foam structures are laminatescontaining the multilayer foam and a laminate layer. Preferably, thelaminate layer can be applied to a side (i.e., surface) of anon-recycled foam layer of the multilayer foam. In these laminates, themultilayer foam structure can, for example, be combined with a filmand/or foil. Examples of suitable materials for such layers include, butare not limited to, polyvinyl chloride (PVC); thermoplastic polyolefin(TPO); thermoplastic urethane (TPU); fabrics such as polyester,polypropylene, cloth and other fabrics; leather and/or fiber layers suchas non-wovens. Such layers may be manufactured using standard techniquesthat are well known to those of ordinary skill in the art. Importantly,the multilayer foam of the disclosure may be laminated on one or bothsides with these materials and may include multiple other layers. If themultilayer foam is laminated on both sides, preferably these laminatelayers can be applied to sides of non-recycled foam layers of themultilayer foam.

In these laminates, a layer may be joined to an adjacent layer by meansof chemical bonds, mechanical means, or combinations thereof. Adjacentlaminate layers may also be affixed to each other by any other meansincluding the use of attractive forces between materials having oppositeelectromagnetic charges or attractive forces present between materialswhich both have either a predominantly hydrophobic character or apredominantly hydrophilic character.

In some embodiments, the multilayer foam structures or laminates areused in automobile interior parts such as door panels, door rolls, doorinserts, door stuffers, trunk stuffers, armrests, center consoles, seatcushions, seat backs, headrests, seat back panels, instrument panels,knee bolsters, or a headliner. These multilayer foam structures orlaminates can also be used in furniture (e.g., commercial, office, andresidential furniture) such as chair cushions, chair backs, sofacushions, sofa trims, recliner cushions, recliner trims, couch cushions,couch trim, sleeper cushions, or sleeper trims. These multilayer foamlaminates or structures can also be used in walls such as modular walls,moveable walls, wall panels, modular panels, office system panels, roomdividers, or portable partitions. The multilayer foam laminates orstructures can also be used in storage casing (e.g., commercial, officeand residential) which can be either mobile or stationary. Furthermore,the multilayer foam laminates and structures can also be used incoverings such as chair cushion coverings, chair back coverings, armrestcoverings, sofa coverings, sofa cushion coverings, recliner cushioncoverings, recliner coverings, couch cushion coverings, couch coverings,sleeper cushion coverings, sleeper coverings, wall coverings, andarchitectural coverings.

Some embodiments include a first layer of the disclosed multilayer foamstructure and a second layer selected from the group consisting of asolid hardwood floor panel, an engineered wood floor panel, a laminatefloor panel, a vinyl floor tile, a ceramic floor tile, a porcelain floortile, a stone floor tile, a quartz floor tile, a cement floor tile, anda concrete floor tile. As stated above, preferably the second layer(s)can be applied to a side (i.e., surface) of the non-recycled layer(s) ofthe multilayer foam structure.

In these laminates, the first layer may be joined to the adjacent panelor tile by means of chemical bonds, mechanical means, or a combinationthereof. The adjacent laminate layers may also be affixed to each otherby any other means including the use of attractive forces betweenmaterials having opposite electromagnetic charges or attractive forcespresent between materials which both have either a predominantlyhydrophobic character or a predominantly hydrophilic character.

A popular method of attaching the disclosed multilayer foam to a floorpanel—particularly a solid hardwood floor panel, an engineered woodfloor panel, and a laminate floor panel—can be via a pressure sensitiveadhesive layer that can be disposed on at least a portion of the foamsurface and/or panel surface. Preferably, the adhesive layer can bedisposed on the surface of a non-recycled layer of the multilayer foamstructure. Any pressure sensitive adhesive known in the art may be used.Examples of such pressure sensitive adhesives are acrylic polymers,polyurethanes, thermoplastic elastomers, block copolymers, polyolefins,silicones, rubber based adhesives, copolymers of ethylhexylacrylate andacrylic acid, copolymers of isooctyl acrylate and acrylic acid, blendsof acrylic adhesives and rubber based adhesives as well as combinationsof the foregoing.

The multilayer foam attached to the floor panel—particularly a solidhardwood floor panel, an engineered wood floor panel, and a laminatefloor panel—serves several purposes. The foam can reduce the reflectedsound pressure level when the panel is impacted, for example, whenwalking on the panel with boots or high heeled shoes. The foam can alsoact as a moisture vapor barrier between the panel and sub-floor and canhelp provide a more uniform laydown among multiple panels since anyunevenness, bumps, or spikes (for example a protruding nailhead) on thesub-floor will be buffered by the foam. These floor panels and tiles arecommonly installed in residential homes, office buildings, and othercommercial buildings.

Another embodiment of the present invention provides a flooring systemincluding: a top floor layer; a sub-floor layer; and one or moreunderlayment layers where at least one of the underlayment layerscontains the disclosed multilayer foam structure disposed between thesub-floor and the top floor layer. Preferably, the sub-floor and the topfloor layers can be applied to sides/surfaces of non-recycled layers ofthe multilayer foam structure.

In this system, the foam layer may or may not be joined to any adjacentlayer, including the sub-floor or the top floor layer. When any layer inthe disclosed system is joined, the attachment can be performed by meansof chemical bonds, mechanical means, or combinations thereof. Theadjacent layers may also be affixed to each other by any other meansincluding the use of attractive forces between materials having oppositeelectromagnetic charges or attractive forces present between materialswhich both have either a predominantly hydrophobic character or apredominantly hydrophilic character.

If any layers are attached, a popular method of attachment can be theuse of either a one component urethane adhesive, a two componenturethane adhesive, a one component acrylic adhesive, or a two componentacrylic adhesive. The adhesive can be applied during the installation ofthe system in residential homes, office buildings, and commercialbuildings.

The foam in this system serves several purposes. The foam can reduce thereflected sound pressure level when the top floor layer is impacted, forexample, when walking on the panel with boots or high heeled shoes. Thefoam can also act as a moisture vapor barrier between the panel andsub-floor and help provide a more uniform laydown among multiple panelssince any unevenness, bumps, or spikes (for example a protrudingnailhead) on the sub-floor will be buffered by the foam. For cases wherethe top floor layer is composed of ceramic floor tiles, porcelain floortiles, stone floor tiles, quartz floor tiles, cement floor tiles, andconcrete floor tiles connected by grout and where all layers in theflooring system are joined, the foam can help reduce grout fracturing bybuffering varying thermal expansions and contractions of the variouslayers in the system.

To satisfy the requirements of any of the above applications, thedisclosed structures of the present disclosure may be subjected tovarious secondary processes, including and not limited to, embossing,corona or plasma treatment, surface roughening, surface smoothing,perforation or microperforation, splicing, slicing, skiving, layering,bonding, and hole punching.

EXAMPLES

The following Table provides a list of various components anddescriptions of those components used in the following Examples.

TABLE 1 Component Description 7250FL polypropylene/polyethylene randomcopolymer commercially produced by Total Petrochemicals [MFI is about1.3-1.6 (2.16 kg, 230° C.)] 6232 polypropylene/polyethylene randomcopolymer commercially produced by Total Petrochemicals [MFI is about1.7-2.3 (2.16 kg, 230° C.)] Infuse ™ polyethylene/octene metalloceneblock copolymer (with OBC 9107 a controlled block sequence) commerciallyproduced by Dow [MFI is about 0.75-1.25 (2.16 kg, 190° C.)] Adflex ™reactor produced thermoplastic polyolefin (rTPO) Q100F commerciallyproduced by LyondellBasell [MFI is about 0.5-0.7 (2.16 kg, 230° C.)]LLP8501.67 linear low density polyethylene (LLDPE)/hexane copolymercommercially produced by ExxonMobil [MFI is about 5.9-7.5 (2.16 kg, 190°C.)] ADCA TC-18I azodicarbonamide commercially produced by P. T. LautenOtsuka Chemical DVB DVB HP (80% DVB) commercially produced by Dow PR023a Toray Plastics (America), Inc. standard compounded antioxidant packagefor polyolefin foam consisting of 14% antioxidants, 0.35% calciumstearate, and 85.65% low density polyethylene (LDPE) carrier resinTPM11166 an extrusion processing aid blend compounded in an LDPE carrierresin commercially produced by Techmer PM recycled Factory scrapmetalized homopolymer polypropylene resin (hPP) based film metalizedwith about 0.02-0.05 μm of physical vapor deposited aluminum that wasshredded and recycled into extrudable oval pellets recycledcryogenically pulverized factory scrap crosslinked crosslinkedpolypropylene/polyethylene blended foam foam (PP-PE-X-E): The sizedistribution of the pulverized foam particles were measured using aRo-Tap ® sieve shaker with U.S. Standard Sieves constructed according toASTM E11. The particle size distribution was measured as: 20 U.S.Standard Sieve: 0.0% 30 U.S. Standard Sieve: 2.5% 40 U.S. StandardSieve: 26.7% 60 U.S. Standard Sieve: 31.6% 80 U.S. Standard Sieve: 14.4%100 U.S. Standard Sieve: 6.6% Pan: 18.2% (All examples in thisdisclosure were coextruded using feed block manifolds)

Example 1—AB Article where A=Foam & B=Film

Components A (i.e., foam layer components) including resins (50 wt. %Infuse™ OBC 9107, 40 wt. % 6232, and 10 wt. % Adflex™ Q100F), chemicalfoaming agent (7.5% PPHR ADCA), crosslinking promoter (2.5% PPHR DVB),antioxidants (5.5% PPHR PR023), and processing aid (2.0% PPHR TPM11166)were fed into a first extruder. The first extruder extruded theComponents A at a specific energy of 12.1 kW·hr/kg and a temperature of173° C. Components B (i.e., film layer components) including resins (100wt. % Adflex™ Q100F), antioxidants (2.75% PPHR PR023), and processingaid (2.0% PPHR TPM11166) were fed into a second extruder. As the firstextruder extruded Components A, the second extruder simultaneouslyextruded Components B at a specific energy of 39.2 kW-hr/kg and atemperature of 201° C.

Components A and Components B were coextruded using an 80/20 feed blockmanifold to produce an uncrosslinked, unfoamed multilayer sheet of about1.33 mm thickness (the unfoamed A layer is about 0.97 mm thick and theunfoamed B layer is about 0.36 mm thick). FIG. 1C is a backlit magnifiedphotograph of a thin slice of the unfoamed multilayer sheet. Afterco-extrusion, the sheet was crosslinked by electron beam radiation at adosage of 45 kGy with Components B layer (i.e., the film layer) facingthe radiation source. In addition, the radiation voltage (650 kv) wasselected such that the exposure was fairly uniform throughout the depthof the sheet.

After crosslinking, the sheet was heated on both surfaces to about 450°F. to obtain a multilayer foam structure of 3.98 mm average thicknessand 0.102 g/cm³ average overall density. The foam layer was about 3.88mm thick and the film layer was about 0.10 mm thick. In addition, theoverall average gel fraction percentage (crosslinking percentage) of themultilayer foam structure was 45.7%. FIG. 1A is a backlit magnifiedphotograph of the Example 1 foam that's been thinly sliced. FIG. 1B is afrontlit non-magnified photograph of the Example 1 foam that's beenthinly sliced. The skin layer is visible in both FIGS. 1A-1B.

Example 2—A/B Article where A=Foam & B=Foam

Components A (i.e., 1^(st) foam layer components) including resins (50wt. % Infuse™ OBC 9107, 40 wt. % 6232, and 10 wt. % Adflex™ Q100F),chemical foaming agent (7.5% PPHR ADCA), crosslinking promoter (2.5%PPHR DVB), antioxidants (5.5% PPHR PR023), and processing aid (2.0% PPHRTPM11166) were fed into a first extruder. The first extruder extrudedthe Components A at a specific energy of 11.5 kW·hr/kg and a temperatureof 173° C. Components B (i.e., 2^(nd) foam layer components) includingresins (40 wt. % 7250FL, 32.5 wt. % 6232, 15 wt. % Adflex™ Q100F, 12.5wt. % LLP8501.67), chemical foaming agent (7.5% PPHR ADCA), crosslinkingpromoter (2.75% PPHR DVB), antioxidants (5.0% PPHR PR023), andprocessing aid (2.0% PPHR TPM11166) were fed into a second extruder. Asthe first extruder extruded Components A, the second extrudersimultaneously extruded Components B at a specific energy of 15.5kW·hr/kg and a temperature of 168° C.

Components A and Components B were coextruded using an 80/20 feed blockmanifold to produce an uncrosslinked, unfoamed multilayer sheet of about1.05 mm thickness (the unfoamed A layer is about 0.80 mm thick and theunfoamed B layer is about 0.25 mm thick). FIG. 2C is a backlit magnifiedphotograph of a thin slice of the unfoamed multilayer sheet. Afterco-extrusion, the sheet was crosslinked by electron beam radiation at adosage of 45 kGy with Components B layer (i.e., the 2^(nd) foam layer)facing the radiation source. In addition, the radiation voltage (650 kv)was selected such that the exposure was fairly uniform throughout thedepth of the sheet.

After crosslinking, the sheet was heated on both surfaces to about 450°F. to obtain a multilayer foam structure of 2.24 mm average thicknessand 0.133 g/cm³ average overall density. The 1^(st) foam layer was about1.61 mm thick and the 2^(nd) foam layer was about 0.63 mm thick. Inaddition, the overall average gel fraction percentage (crosslinkingpercentage) of the multilayer foam structure was 46.7%. FIG. 2A is abacklit magnified photograph of Example 2 foam that's been thinlysliced. FIG. 2B is a frontlit non-magnified photograph of Example 2 foamthat's been thinly sliced.

Example 3—A/B/A Article where A=Foam & B=Foam Including RecycledMetallized Polyolefin Material

Components A (i.e., 1^(st) and 3^(rd) foam layer components) includingresins (40 wt. % 7250FL, 32.5 wt. % 6232, 15 wt. % Adflex™ Q100F, 12.5wt. % LLP8501.67), chemical foaming agent (7.5% PPHR ADCA), crosslinkingpromoter (2.75% PPHR DVB), antioxidants (5.0% PPHR PR023), andprocessing aid (2.0% PPHR TPM11166) were fed into a first and thirdextruder. The first and third extruders extruded the Components A at aspecific energy of 18.3 kW·hr/kg and a temperature of 172° C. ComponentsB (i.e., 2^(nd) recycled foam layer components) including resins (40 wt.% 7250FL, 32.5 wt. % 6232, 15 wt. % recycled resin, 12.5 wt. %LLP8501.67), chemical foaming agent (7.5% PPHR ADCA), crosslinkingpromoter (2.75% PPHR DVB), antioxidants (5.0% PPHR PR023), andprocessing aid (2.0% PPHR TPM11166) were fed into a second extruder. Asthe first and third extruders extruded Components A, the second extrudersimultaneously extruded Components B at a specific energy of 16.4kW·hr/kg and a temperature of 169° C.

Components A and Components B were coextruded using an 25/50/25 feedblock manifold to produce an uncrosslinked, unfoamed multilayer sheet ofabout 1.04 mm thickness (the unfoamed A layers are about 0.26 and 0.28mm thick and the unfoamed B layer is about 0.50 mm thick). FIG. 3E is abacklit magnified photograph of a thin slice of the unfoamed multilayersheet. After co-extrusion, the sheet was crosslinked by electron beamradiation at a dosage of 45 kGy. In addition, the radiation voltage (650kv) was selected such that the exposure was fairly uniform throughoutthe depth of the sheet.

After crosslinking, the sheet was heated on both surfaces to about 450°F. to obtain a multilayer foam structure of 2.05 mm average thicknessand 0.208 g/cm³ average overall density, wherein the 1^(st) and 3^(rd)foam layers sandwich the 2^(nd) recycled foam layer. The 1^(st) and3^(rd) foam layers combined were about 1.06 mm thick (each about 0.53mm) and the 2^(nd) recycled foam layer was about 0.99 mm thick. Inaddition, the overall average gel fraction percentage (crosslinkingpercentage) of the multilayer foam structure was 43.2%. FIGS. 3A-3B arebacklit magnified photographs of the Example 3 foam that's been thinlysliced. FIGS. 3C-3D are frontlit non-magnified photographs of theExample 3 foam that's been thinly sliced.

Example 4—A/B/A Article where A=Foam & B=Foam Including RecycledCryogenically Pulverized Foam Material

Components A (i.e., 1^(st) and 3^(rd) foam layer components) includingresins (40 wt. % 7250FL, 32.5 wt. % 6232, 15 wt. % Adflex™ Q100F, 12.5wt. % LLP8501.67), chemical foaming agent (7.5% PPHR ADCA), crosslinkingpromoter (2.75% PPHR DVB), antioxidants (5.0% PPHR PR023), andprocessing aid (2.0% PPHR TPM11166) were fed into a first and thirdextruder. The first and third extruders extruded the Components A at aspecific energy of 18.3 kW·hr/kg and a temperature of 172° C. ComponentsB (i.e., 2^(nd) recycled foam layer components) including resins (40 wt.% 7250FL, 32.5 wt. % 6232, 15 wt. % recycled crosslinked foam, 12.5 wt.% LLP8501.67), chemical foaming agent (7.5% PPHR ADCA), crosslinkingpromoter (2.75% PPHR DVB), antioxidants (5.0% PPHR PR023), andprocessing aid (2.0% PPHR TPM11166) were fed into a second extruder. Asthe first and third extruders extruded Components A, the second extrudersimultaneously extruded Components B at a specific energy of 17 kW·hr/kgand a temperature of 170° C.

Components A and Components B were coextruded using an 25/50/25 feedblock manifold to produce an uncrosslinked, unfoamed multilayer sheet ofabout 1.11 mm thickness (the unfoamed A layers are about 0.26 and 0.25mm thick and the unfoamed B layer is about 0.60 mm thick). FIG. 4C is abacklit magnified photograph of a thin slice of the unfoamed multilayersheet. After co-extrusion, the sheet was crosslinked by electron beamradiation at a dosage of 45 kGy. In addition, the radiation voltage (650kv) was selected such that the exposure was fairly uniform throughoutthe depth of the sheet.

After crosslinking, the sheet was heated on both surfaces to about 450°F. to obtain a multilayer foam structure of 3.60 mm average thicknessand 0.130 g/cm³ average overall density, wherein the 1^(st) and 3^(rd)foam layers sandwich the 2^(nd) recycled foam layer. The 1^(st) and3^(rd) foam layers combined were about 1.90 mm thick (each about 0.95mm) and the 2^(nd) recycled foam layer was about 1.70 mm thick. Inaddition, the overall average gel fraction percentage (crosslinkingpercentage) of the multilayer foam structure was 37.9%. FIG. 4A is abacklit magnified photograph of the Example 4 foam. FIG. 4B is afrontlit non-magnified photograph of the Example 4 foam. Note that inExample 4, the recycled, crosslinked foam material was a charcoal colorand this is the reason why the middle layer is darker.

Extrusion Foaming Vs. Extruding then Foaming

A polyethylene extrusion foamed sheet (a 0.025-0.026 g/cm³ pool linerwall foam commercially available from the Gladon Company (Oak Creek,Wis.) (“38064 blue Gladon”)) was compared to two 0.025-0.026 g/cm³polyethylene foam sheets produced by the methods disclosed herein. Thefirst sheet is Toraypef® 40100-AG00 commercially produced by TorayIndustries, Inc (Shiga, JP). The 40100-AG00 was foamed by heating theradiation crosslinked sheet with hot air. The second sheet is Toraypef®40064LCE-STD produced by Toray Plastics (America), Inc. The 40064LCE-STDwas foamed by heating the radiation crosslinked sheet by molten salt onone surface and radiant heat on the other surface. The surfacecharacteristics of these three Examples were tested using a NanoveaST400 3D Profilometer. The probe specifications and measurementparameters can be found in Tables 2 and 3 below. As shown in Table 4below, regardless of the heating method, the extrusion foamed material(38064 blue Gladon) is significantly rougher (exhibiting a mean surfaceroughness (Sa) of 83.9 μm and a maximum height (height between thehighest peak and the deepest valley) (Sz) of 706 μm) than the extrudedthen foamed sheets (40100-AG00 & 40064LCE-STD) (exhibiting a meansurface roughness (Sa) between 20.7-65.2 μm and a maximum height (Sz) of237-592 μm).

Chemically Crosslinked Vs. Physically Crosslinked

The surface of a 0.067 g/cm³ chemically crosslinked polyolefin foamsheet (ProGame™ XC-Cut 7010 commercially produced by Trocellen Group ofCompanies) was compared to two 0.067 g/cm³ physically crosslinkedpolypropylene/polyethylene blended foam sheets (Toraypef® 15030AC17-STD& ToraSoft® 15030SR18-STD) produced by the methods disclosed herein.Both the chemically crosslinked foam and the physically crosslinkedfoams were foamed in a post-extrusion process. The surfacecharacteristics of these three Examples were tested using a NanoveaST400 3D Profilometer. The probe specifications and measurementparameters can be found in Tables 2 and 3 below. As shown in Table 4below, the chemically crosslinked foam (XC-Cut 7010) exhibited a meansurface roughness (Sa) of 89.5 μm and a maximum height (Sz) of 856 μm.The physically crosslinked foams exhibited a mean surface roughness (Sa)of 7.63-23.9 μm and a maximum height (Sz) of 81.0-273 μm. Thus, thephysically crosslinked foams exhibit significantly smoother surfacesversus the chemically crosslinked foam.

TABLE 2 Measurement Range P1-OP400C P1-OP1200C Z Resolution (nm) 12 25 ZAccuracy (nm) 60 200 Lateral Resolution (μm) 3.5 4.0

TABLE 3 400100-AG00, 40064 LCE-STD, 40064 LCE-STD 15030AC17-STD,unlabeled side, 15030SR18-STD 38064, XC-Cut 7010 Probe P1-OP400CP1-OP1200C Acquisition rate 800-1850 Hz 200-1500 Hz Averaging 1 1Measured surface 10 mm × 10 mm 10 mm × 10 mm Step size 10 μm × 15 μm 10μm × 15 μm Measurement Time 00:49:23 01:31:45

TABLE 4 Sample Sa (μm) Sz (μm) 400100-AG00 labeled side 20.7 237400100-AG00 unlabeled side 29.5 276 40064 LCE-STD labeled side 22.8 28140064 LCE-STD unlabeled side 65.2 592 38064 blue Gladon 83.9 70615030AC17-STD labeled side 22.7 273 15030AC17-STD unlabeled side 7.6381.0 15030SR18-STD labeled side 23.9 261 15030SR18-STD unlabeled side12.7 149 XC-Cut 7010 “15100” 89.5 856Test Methods

The various properties in the above examples were measured by thefollowing methods:

The specific energy of an extruder can be calculated according to theformula:

${{{Specific}\mspace{14mu}{Energy}} = \frac{{KW}\mspace{14mu}({applied})}{{feedrate}\mspace{14mu}\left( \frac{kg}{hr} \right)}},{where}$${{KW}\mspace{14mu}({applied})} = \frac{\begin{matrix}{{KW}\mspace{14mu}\left( {{motor}\mspace{14mu}{rating}} \right)*} \\{\left( {\%\mspace{14mu}{torque}\mspace{14mu}{from}\mspace{14mu}{maximum}\mspace{14mu}{allowable}} \right)*} \\{{RPM}\left( {{actual}\mspace{14mu}{running}\mspace{14mu}{RPM}} \right)}\end{matrix}}{\begin{matrix}{{Max}\mspace{14mu}{{RPM}\left( {{capability}\mspace{14mu}{of}\mspace{14mu}{extruder}} \right)}*} \\{0.97\left( {{gearbox}\mspace{14mu}{efficiency}} \right)}\end{matrix}}$

In general, preferred values of specific energy would be at least 0.090kW·hr/kg, preferably at least 0.105 kW·hr/kg, and more preferably atleast 0.120 kW·hr/kg, and even more preferably at least 10 kW·hr/kg.

The “density” of the multilayer foam structure can be defined andmeasured using section or “overall” density, rather than a “core”density, according to JIS K6767. In general, preferred values of densitywould be 20-250 kg/m³, and more preferably 30-125 kg/m³.

The “mean surface roughness” and “maximum height” (height between thehighest peak and the deepest valley) of the multilayer foam structure'ssurface can be defined and measured using a Nanovea 3D Non-ContactProfilometer. The probe specifications and measurement parameters formeasuring the mean surface roughness and maximum height can be found inTables 2 and 3. The mean surface roughness for the foams produced can beless than about 80 μm, less than about 70 μm, less than about 50 μm,less than about 40 μm, less than about 30 μm, less than about 25 μm,less than about 20 μm, less than about 15 μm, and less than about 10 μm.The maximum height for the surface of foams produced can be less thanabout 700 μm, less than about 600 μm, less than about 300 μm, less thanabout 250 μm, less than about 200 μm, less than about 150 μm, and lessthan 100 μm.

“Crosslinking” can be measured according to the “Toray Gel FractionMethod,” where tetralin solvent is used to dissolve non-crosslinkedcomponents. In principle, non-crosslinked material is dissolved intetralin and the crosslinking degree is expressed as the weightpercentage of crosslinked material. The apparatus used to determine thepercent of polymer crosslinking includes: 100 mesh (0.0045 inch wirediameter); Type 304 stainless steel bags; numbered wires and clips; aMiyamoto thermostatic oil bath apparatus; an analytical balance; a fumehood; a gas burner; a high temperature oven; an anti-static gun; andthree 3.5 liter wide mouth stainless steel containers with lids.Reagents and materials used include tetralin high molecular weightsolvent, acetone, and silicone oil. Specifically, an empty wire mesh bagis weighed and the weight recorded. For each sample, about 100milligrams±about 5 milligrams of sample is weighed out and transferredto the wire mesh bag. The weight of the wire mesh bag and the sample,typically in the form of foam cuttings, is recorded. Each bag isattached to the corresponding number wire and clips. When the solventtemperature reaches 130° C., the bundle (bag and sample) is immersed inthe solvent. The samples are shaken up and down about 5 or 6 times toloosen any air bubbles and fully wet the samples. The samples areattached to an agitator and agitated for three (3) hours so that thesolvent can dissolve the foam. The samples are then cooled in a fumehood. The samples are washed by shaking up and down about 7 or 8 timesin a container of primary acetone. The samples are washed a second timein a second acetone wash. The washed samples are washed once more in athird container of fresh acetone as above. The samples are then hung ina fume hood to evaporate the acetone for about 1 to about 5 minutes. Thesamples are then dried in a drying oven for about 1 hour at 120° C. Thesamples are cooled for a minimum of about 15 minutes. The wire mesh bagis weighed on an analytical balance and the weight is recorded.Crosslinking is then calculated using the formula 100*(C−A)/(B−A), whereA=empty wire mesh bag weight; B=wire bag weight+foam sample beforeimmersion in tetralin; and C=wire bag weight+dissolved sample afterimmersion in tetralin. In general, preferred values of crosslinkingdegree can be 20-75%, and more preferably 30-60%.

The “melt flow index” (MFI) value for a polymer can be defined andmeasured according to ASTM D1238 at 230° C. for polypropylenes andpolypropylene based materials and at 190° C. for polyethylenes andpolyethylene based materials using a 2.16 kg plunger for 10 minutes. Thetest time may be reduced for relatively high melt flow resins.

This application discloses several numerical ranges in the text andfigures. The numerical ranges disclosed inherently support any range orvalue within the disclosed numerical ranges even though a precise rangelimitation is not stated verbatim in the specification because thisinvention can be practiced throughout the disclosed numerical ranges.

The above description is presented to enable a person skilled in the artto make and use the invention, and is provided in the context of aparticular application and its requirements. Various modifications tothe preferred embodiments will be readily apparent to those skilled inthe art, and the generic principles defined herein may be applied toother embodiments and applications without departing from the spirit andscope of the invention. Thus, this invention is not intended to belimited to the embodiments shown, but is to be accorded the widest scopeconsistent with the principles and features disclosed herein. Finally,the entire disclosure of the patents and publications referred in thisapplication are hereby incorporated herein by reference.

What is claimed as new and desired to be protected by Letters Patent ofthe United States is:
 1. A multilayer foam structure comprising: acoextruded first foam layer comprising polypropylene or polyethylene;and a coextruded second foam layer on a side of the first foam layer,the second foam layer comprising: 5-50 wt. % recycled, crosslinkedpolyolefin foam material; and 50-95 wt. % polypropylene, polyethylene,or a combination of polypropylene and polyethylene.
 2. The multilayerfoam structure of claim 1, further comprising a coextruded third foamlayer on a side of the second foam layer opposite the first foam layer,the third foam layer comprising polypropylene or polyethylene.
 3. Themultilayer foam structure of claim 2, wherein the first foam layer andthe third foam layer are substantially free of recycled polyolefinmaterial.
 4. The multilayer foam structure of claim 1, wherein therecycled, crosslinked polyolefin foam material comprises cryogenicallypulverized polyolefin foam material.
 5. The multilayer foam structure ofclaim 1, wherein the first layer comprises polypropylene with a meltflow index of 0.1-25 grams per 10 minutes at 230° C.
 6. The multilayerfoam structure of claim 1, wherein first layer comprises polyethylenewith a melt flow index of 0.1-25 grams per 10 minutes at 190° C.
 7. Themultilayer foam structure of claim 1, wherein the density of themultilayer foam structure is 20-250 kg/m³.
 8. The multilayer foamstructure of claim 1, wherein the multilayer foam structure has acrosslinking degree of 20-75%.
 9. The multilayer foam structure of claim1, wherein the multilayer foam structure has an average closed cell sizeof 0.05-1.0 mm.
 10. The multilayer foam structure of claim 1, whereinthe multilayer foam structure has a thickness of 0.2-50 mm.
 11. Themultilayer foam structure of claim 1, wherein a mean surface roughnessfor the first foam layer is less than 80 μm.
 12. The multilayer foamstructure of claim 2, wherein the first layer and third layer comprisepolypropylene and polyethylene.
 13. The multilayer foam structure ofclaim 1, wherein the foam structure is slit, friction sawed, sheared,heat cut, laser cut, plasma cut, water jet cut, die-cut, mechanicallycut, or manually cut to form an article.
 14. A laminate comprising: amultilayer foam structure comprising: a coextruded first foam layercomprising polypropylene or polyethylene; and a coextruded second foamlayer on a side of the first foam layer, the second foam layercomprising: 5-50 wt. % recycled, crosslinked polyolefin foam material;and 50-95 wt. % polypropylene, polyethylene, or a combination ofpolypropylene and polyethylene; and a laminate layer on a side of thefirst foam layer opposite the second foam layer.
 15. The laminate ofclaim 14, wherein the recycled, crosslinked polyolefin foam materialcomprises cryogenically pulverized polyolefin foam material.
 16. Thelaminate of claim 14, wherein the laminate layer is selected from thegroup consisting of a film, a fabric, a fiber layer, and a leather. 17.The laminate of claim 14, wherein a mean surface roughness for the firstfoam layer is less than 80 μm.
 18. The laminate of claim 14, wherein themultilayer foam structure further comprises a third foam layer on a sideof the second foam layer opposite the first foam layer, the third foamlayer comprising polypropylene or polyethylene.
 19. The laminate ofclaim 18, wherein the first foam layer and the third foam layer aresubstantially free of recycled polyolefin material.
 20. The laminate ofclaim 18, further comprising a substrate on a side of the third foamlayer opposite the second foam layer, wherein the laminate isthermoformed onto the substrate.
 21. The laminate of claim 18, whereinthe first layer and third layer comprise polypropylene and polyethylene.